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author:

Yu, Changlin (Yu, Changlin.) [1] | Cao, Fangfang (Cao, Fangfang.) [2] | Li, Gao (Li, Gao.) [3] | Wei, Rongfu (Wei, Rongfu.) [4] | Yu, Jimmy C. (Yu, Jimmy C..) [5] | Jin, Rongchao (Jin, Rongchao.) [6] | Fan, Qizhe (Fan, Qizhe.) [7] | Wang, Chunying (Wang, Chunying.) [8]

Indexed by:

EI Scopus SCIE

Abstract:

Novel noble metal (Rh, Pd, Pt)/BiOX(Cl, Br, I) composite photocatalysts were prepared and well characterized by nitrogen-physical adsorption, powder X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV-vis diffuse reflectance spectra (DRS), X-ray photoelectron spectroscopy (XPS), and photoluminescence (PL) emission spectroscopy. The effects of noble metals deposition on the optical and photocatalytic performance of BiOX in degradation of the acid orange II dye under both UV and visible light irradiation were systematically investigated. Results show that noble metal depositions enhance their visible light absorption and photocatalytic performance. However, catalytic activity is controlled by the species and concentration of noble metal. Over BiOCl, the noble metals, abilities to promote activity are in the orders Pt > Pd > Rh and Rh > Pt > Pd under UV light and visible light irradiation, respectively. Over different BiOX with optimal noble metal content, the best UV light activities are in the order Pd(0.5%)/BiOBr > Pt(1%)/BiOCl > Pd(2%)/BiOCl. Under visible light illumination, the best activities change to Pd(4%)/BiOBr > Pd(0.5%)/BiOI > Rh(1%)/BiOCl. The enhanced photocatalytic efficiency could be attributed to the promoted separation rate of photo-generated e(-)/h(+) pairs and the role of plasmon photocatalysis caused by deposited noble metal nanoparticles. (C) 2013 Elsevier B.V. All rights reserved.

Keyword:

Bismuth oxyhalide Enhanced mechanism Noble metal nanoparticle Photocatalysis Plasmon photocatalysis

Community:

  • [ 1 ] [Yu, Changlin]Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, Ganzhou 341000, Jiangxi, Peoples R China
  • [ 2 ] [Cao, Fangfang]Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, Ganzhou 341000, Jiangxi, Peoples R China
  • [ 3 ] [Wei, Rongfu]Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, Ganzhou 341000, Jiangxi, Peoples R China
  • [ 4 ] [Fan, Qizhe]Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, Ganzhou 341000, Jiangxi, Peoples R China
  • [ 5 ] [Wang, Chunying]Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, Ganzhou 341000, Jiangxi, Peoples R China
  • [ 6 ] [Yu, Changlin]Carnegie Mellon Univ, Dept Chem, Pittsburgh, PA 15213 USA
  • [ 7 ] [Li, Gao]Carnegie Mellon Univ, Dept Chem, Pittsburgh, PA 15213 USA
  • [ 8 ] [Jin, Rongchao]Carnegie Mellon Univ, Dept Chem, Pittsburgh, PA 15213 USA
  • [ 9 ] [Cao, Fangfang]Fuzhou Univ, State Key Lab Breeding Base, Fujian Prov Key Lab Photocatalysis, Fuzhou 350002, Peoples R China
  • [ 10 ] [Yu, Jimmy C.]Chinese Univ Hong Kong, Ctr Novel Funct Mol, Dept Chem, Shatin, Hong Kong, Peoples R China
  • [ 11 ] [Yu, Jimmy C.]Chinese Univ Hong Kong, Environm Sci Programme, Shatin, Hong Kong, Peoples R China

Reprint 's Address:

  • [Yu, Changlin]Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, 86 Hongqi Rd, Ganzhou 341000, Jiangxi, Peoples R China

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Source :

SEPARATION AND PURIFICATION TECHNOLOGY

ISSN: 1383-5866

Year: 2013

Volume: 120

Page: 110-122

3 . 0 6 5

JCR@2013

8 . 2 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 153

SCOPUS Cited Count: 167

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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