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The bulk nanocrystalline magnets of Nd10Y1Fe85-xNb3.5Ti0.5Bx (x = 14-22) and Nd10Y1Fe69Nb3.5M0.5B16 (M = Ti, Zr, Cr, Mo) in rod form with a diameter of 1.5 mm were prepared by copper mold injection casting. The magnetic properties, microstructure and corrosion behavior of bulk magnets have been studied. It is shown that the glass forming ability of alloy is obviously improved with increasing the B content. For the Nd10Y1Fe85-xNb3.5Ti0.5Bx (x = 14-22) alloys, the optimal magnetic properties of B-r = 6.0 kG, H-i(c) = 7.8 - kOe and (BH)(max) = 6.7 MGOe can be achieved when x = 16, although the sample of x = 22 exhibits better corrosion resistance than the sample of x = 16. For the Nd10Y1Fe69Nb3.5M0.5B16 (M = Ti, Zr, Cr, Mo) alloys, the sample of M = Zr exhibits the best magnetic energy product of (BH)(max) = 7.0 MGOe, with B-r = 6.3 kG and H-i(c) = 8.2 kOe. While, the highest intrinsic coercivity of H-i(c) = 8.8 kOe, with B-r = 5.6 kG and (BH)(max) = 5.8 MGOe is obtained in the sample of M = Mo. The electrochemistry analysis shows that the Zr-doped sample has the best corrosion resistance among the M-doped alloys. The thermogravimetric analysis reveals that the oxidation rates of bulk magnets are significantly enhanced when the temperature is above 350 degrees C, and the Ti-doped sample has the best antioxidant ability among the M-doped alloys. (C) 2012 Elsevier B. V. All rights reserved.
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JOURNAL OF ALLOYS AND COMPOUNDS
ISSN: 0925-8388
Year: 2013
Volume: 555
Page: 16-21
2 . 7 2 6
JCR@2013
5 . 8 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 10
SCOPUS Cited Count: 14
ESI Highly Cited Papers on the List: 0 Unfold All
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Chinese Cited Count:
30 Days PV: 0
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