Ordered　mesoporous　carbons　(OMCs)　with　well-developed　mesopores　were　synthesized　using　evaporation-induced　self-assembly　(EISA).　The　triblock　copolymer　P123/phenol-resin/silica　composites　were　prepared　by　EISA　using　tetraethyl　orthosilicate　as　the　inorganic　source,　P123　as　the　structure　directing　agent　and　phenol-resin　as　the　carbon　source.　OMCs　were　obtained　by　the　carbonization　of　the　composites,　followed　by　the　removal　of　the　silica　template　with　a　mass　fraction　10%　HF　aqueous　solution.　For　comparison,　another　OMC　was　synthesized　by　using　ordered　silica　as　a　hard　template　and　impregnated　sucrose　as　the　carbon　precursor.　The　samples　were　characterized　by　scanning　and　transmission　electron　microscopy　and　N-2　sorption.　Results　indicated　that　the　OMCs　had　an　ordered　hexagonal　structure　with　a　narrow　distribution　of　mesopores.　The　optimized　OMC　was　obtained　using　a　P123/phenol-resin　mass　ratio　of　1　:0.　25.　Compared　with　the　OMCs　synthesized　by　the　hard　template　method,　the　new　OMCs　had　fewer　micro-　and　macropores.