Two　new　organically　templated　copper　halides,　(nbq)(4)Cu4I8　(1)　and　[(ipq)(2)　(Cu5I7)](n)　(2)　have　been　synthesized　in　the　presence　of　nbq(+)　and　ibq(+)　(nbq(+)　=　N-(n-butyl)-quinolinium,　ibq(+)　=　N-(iso-pentyl)-quinolinium)　acting　as　structure-directing　agents(SDAs).　Both　of　the　compounds　present　hybrid　structures　with　SDAs　and　inorganic　moieties　being　incorporated.　In　1,　tetrameric　Cu4I84-　anion　is　composed　by　edge-sharing　CuI4　tetrahedrons　and　CuI3　planar　triangles.　But　the　inorganic　framework　of　2　presents　one-dimensional　arrangement　which　results　from　the　tetrahedron　CuI4　and　pseudo　trigonal　pyramid　CuI3　through　edge-sharing　fashion.　Electrostatic　interactions　between　organic　counter　cations　and　inorganic　moieties　could　be　observed　and　contribute　to　the　crystal　packing.　Both　compounds　are　further　characterized　by　IR,　UV　-　Vis,　elemental　analysis,　fluorescence　and　cyclic　voltammetry.