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author:

Lin, Bingyu (Lin, Bingyu.) [1] (Scholars:林炳裕) | Wang, Rong (Wang, Rong.) [2] (Scholars:王榕) | Lin, Jianxin (Lin, Jianxin.) [3] (Scholars:林建新) | Du, Shuwei (Du, Shuwei.) [4] | Yu, Xiujin (Yu, Xiujin.) [5] (Scholars:俞秀金) | Wei, Kemei (Wei, Kemei.) [6]

Indexed by:

EI Scopus SCIE

Abstract:

A series of Ru/Al2O3 catalysts for ammonia synthesis were prepared by hydrazine reduction of RuCl3 in KOH solution under the mild conditions, and characterized by XRF, TEM and CO chemisorption. The results showed that no chloride remained on the catalysts obtained by hydrazine reduction and the activities of the catalysts with hydrazine treatment were higher than those of conventional hydrogen-reduced catalysts. The particles sizes and the activities of the catalysts were determined by the molar ratios between hydrazine and ruthenium. The most promising catalyst was obtained when the hydrazine/ruthenium ratio was in the range of 1-3. (c) 2007 Elsevier B.V. All rights reserved.

Keyword:

ammonia synthesis chlorine-free hydrazine reduction Ru supported catalysts

Community:

  • [ 1 ] Fuzhou Univ, Natl Res Ctr Chem Fertilizer Catalysts, Fujian 350002, Peoples R China

Reprint 's Address:

  • 王榕

    [Wang, Rong]Fuzhou Univ, Natl Res Ctr Chem Fertilizer Catalysts, 523 Gongye Rd, Fujian 350002, Peoples R China

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Source :

CATALYSIS COMMUNICATIONS

ISSN: 1566-7367

Year: 2007

Issue: 11

Volume: 8

Page: 1838-1842

2 . 3 9 4

JCR@2007

3 . 4 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:2

Cited Count:

WoS CC Cited Count: 56

SCOPUS Cited Count: 58

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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