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Abstract:
The title complex, [Co(C15H12N3O2S)(2)], consists of an octahedrally coordinated Co II ion, with two crystallographically independent 1,4- dibenzoylthiosemicarbazidate ligands in a tridentate mer coordination [ Co - O = 2.064 ( 3) - 2.132 ( 3) A and Co - N = 2.037 ( 3) - 2.043 ( 3) A]. There are intermolecular N - H center dot center dot center dot S hydrogen bonds involving one ligand and strong pi-pi stacking interactions involving the other ligand, resulting in a three- dimensional supramolecular framework. The hydrogen bonds and pi-pi interactions, as well as different intramolecular aryl-benzamide H - C center dot center dot center dot H( - N) distances, give rise to a difference in conformation between the two ligands.
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ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN: 0108-2701
Year: 2007
Volume: 63
Page: M343-M345
0 . 7 1 9
JCR@2007
0 . 3 2 6
JCR@2014
JCR Journal Grade:3
Cited Count:
WoS CC Cited Count: 7
SCOPUS Cited Count: 7
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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