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author:

Ke, Yuan-Zhen (Ke, Yuan-Zhen.) [1] | Zheng, Leng-Feng (Zheng, Leng-Feng.) [2] | Luo, Jian-Hai (Luo, Jian-Hai.) [3] | Huang, Xi-He (Huang, Xi-He.) [4] (Scholars:黄细河) | Huang, Chang-Cang (Huang, Chang-Cang.) [5] (Scholars:黄长沧)

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EI Scopus SCIE

Abstract:

The title complex, [Co(C15H12N3O2S)(2)], consists of an octahedrally coordinated Co II ion, with two crystallographically independent 1,4- dibenzoylthiosemicarbazidate ligands in a tridentate mer coordination [ Co - O = 2.064 ( 3) - 2.132 ( 3) A and Co - N = 2.037 ( 3) - 2.043 ( 3) A]. There are intermolecular N - H center dot center dot center dot S hydrogen bonds involving one ligand and strong pi-pi stacking interactions involving the other ligand, resulting in a three- dimensional supramolecular framework. The hydrogen bonds and pi-pi interactions, as well as different intramolecular aryl-benzamide H - C center dot center dot center dot H( - N) distances, give rise to a difference in conformation between the two ligands.

Keyword:

Community:

  • [ 1 ] Fuzhou Univ, Dept Chem, Fujian 350002, Peoples R China

Reprint 's Address:

  • 黄细河

    [Huang, Xi-He]Fuzhou Univ, Dept Chem, Fujian 350002, Peoples R China

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Source :

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS

ISSN: 0108-2701

Year: 2007

Volume: 63

Page: M343-M345

0 . 7 1 9

JCR@2007

0 . 3 2 6

JCR@2014

JCR Journal Grade:3

Cited Count:

WoS CC Cited Count: 7

SCOPUS Cited Count: 7

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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