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The two trinuclear nickel(II) complexes, Ni-3(C13H15N2O3)(2)(C5H5N)(4) (1) and Ni-3(C13H15N2O3)(2)(C5H5N)(2)(C3H7NO)(2) (2), were prepared by the reaction of Ni(OAc)(2)center dot 4H(2)O with N-hexanoylsahcylhydrazide. The crystal structures of complexes were determined by X-ray diffraction analysis. Complex 1 takes triclinic symmetry with space group P-1 and cell dimensions of a=0.92377(2) nm, b=1.08786(6) nm, c=1.29391(3) nm, alpha=76.395(4)degrees, beta=78.418(3)degrees, gamma=67.378(4)degrees, V=1.15772(7) nm(3), Z= 1, mu=12.63 cm(-1). Complex 2 belongs to triclinic system and P2(1) space group and the crystallographic data: a=1.4889(2) nm, b=1.0389(1) nm, c=1.4994(2) nm, beta=96.174(4)degrees, V=2.3058(5) nm(3), Z=2, mu=12.70 cm(-1). The structures of the two molecules are similar. The three nickel atoms in each molecule of the two title complexes arrange in a strictly linear structure. The central nickel atom of the molecule adopts octahedral configuration, while the two nickel atoms on the two sides adopt square-planar configuration in each molecule. But the central nickel atoms of the two complexes have different axial ligands, which cause a slight difference in the bond distances of the octahedron. The antibacterial activity of compound 1 against seven common bacteria was investigated.
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CHINESE JOURNAL OF CHEMISTRY
ISSN: 1001-604X
CN: 31-1547/O6
Year: 2005
Issue: 10
Volume: 23
Page: 1407-1411
0 . 8 1 9
JCR@2005
5 . 5 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
JCR Journal Grade:3
Cited Count:
WoS CC Cited Count: 17
SCOPUS Cited Count: 18
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 4
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