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Abstract:
The title nickel complex with 1,2-disalicyloylhydrazine, [Ni(en)(3)](2+).H(2)dsh(2-), has been synthesized. It crystallizes in orthorhombic, space group P2(1)2(1)2(1) with a = 10.5094(4), b = 12.5003(8), c = 17.487(1) Angstrom, V = 2297.2(2) Angstrom(3), Z = 4, M-r = 509.26, D-c = 1.472 g/cm(3), mu = 0.889 mm(-1), F(000) = 1080, R = 0.0327 and wR = 0.0375. Six nitrogen atoms of three ethylenediamine ligands in the cation coordinate to the Ni(II) ion, forming a distorted octahedron. The bond distances of Ni(II)-N(en) range from 2.110(3) to 2.151(2) Angstrom. The neighboring molecules of the title complex are linked by intermolecular N-H...O hydrogen bonds between [Ni(en)(3)](2+) dications and H(2)dsh(2-) dianions, forming a two-dimensional network.
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CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
ISSN: 0254-5861
CN: 35-1112/TQ
Year: 2004
Issue: 6
Volume: 23
Page: 687-690
0 . 7 3 4
JCR@2004
5 . 9 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
JCR Journal Grade:3
Cited Count:
WoS CC Cited Count: 2
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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