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author:

Chen, XH (Chen, XH.) [1] | Liu, SX (Liu, SX.) [2]

Indexed by:

SCIE PKU CSCD

Abstract:

The title nickel complex with 1,2-disalicyloylhydrazine, [Ni(en)(3)](2+).H(2)dsh(2-), has been synthesized. It crystallizes in orthorhombic, space group P2(1)2(1)2(1) with a = 10.5094(4), b = 12.5003(8), c = 17.487(1) Angstrom, V = 2297.2(2) Angstrom(3), Z = 4, M-r = 509.26, D-c = 1.472 g/cm(3), mu = 0.889 mm(-1), F(000) = 1080, R = 0.0327 and wR = 0.0375. Six nitrogen atoms of three ethylenediamine ligands in the cation coordinate to the Ni(II) ion, forming a distorted octahedron. The bond distances of Ni(II)-N(en) range from 2.110(3) to 2.151(2) Angstrom. The neighboring molecules of the title complex are linked by intermolecular N-H...O hydrogen bonds between [Ni(en)(3)](2+) dications and H(2)dsh(2-) dianions, forming a two-dimensional network.

Keyword:

1,2-disalicyloylhydrazine crystal structure ethylenediamine nickel complex

Community:

  • [ 1 ] Fuzhou Univ, Cent Lab, Fuzhou 3500002, Peoples R China

Reprint 's Address:

  • 陈小华

    [Chen, XH]Fuzhou Univ, Cent Lab, Fuzhou 3500002, Peoples R China

Email:

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Source :

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY

ISSN: 0254-5861

CN: 35-1112/TQ

Year: 2004

Issue: 6

Volume: 23

Page: 687-690

0 . 7 3 4

JCR@2004

5 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:3

Cited Count:

WoS CC Cited Count: 2

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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