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author:

Liu, SX (Liu, SX.) [1] | Wang, X (Wang, X.) [2]

Indexed by:

Scopus SCIE PKU CSCD

Abstract:

The title complex was prepared and its crystal structure was determined, The crystal is space group  with parameters, a = 1,191 1(2) nm, b = 1.532 2(2) nm, c = 1.049 2(2) nm, a = 108.98(1)degrees, beta = 107.04(1)degrees gamma = 70.25(1)degrees, Z = 2, T = 296 K and the final R = 0.054 1 for 3 998 observed reflections, The Cu atom is five-coordinated with a distorted trigonal bipyramid. Four nitrogen atoms from two 2,2'-dipyridyl ligands and one carboxyl oxygen atom from benzilate form a distorted trigonal plane, while the other two nitrogen atoms from the two 2,2'-dipyridyl ligands occupy the two axial positions. The assignment in IR spectrum is discussed.

Keyword:

benzilate copper complex crystal structure IR spectrum

Reprint 's Address:

  • 刘世雄

    [Liu, SX]FUZHOU UNIV,DEPT CHEM,FUZHOU 350002,PEOPLES R CHINA

Email:

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Source :

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE

ISSN: 0251-0790

CN: 22-1131/O6

Year: 1996

Issue: 2

Volume: 17

Page: 169-172

0 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

Cited Count:

WoS CC Cited Count: 6

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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