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author:

Liu, Shusheng (Liu, Shusheng.) [1] | Cheng, Xiansu (Cheng, Xiansu.) [2] (Scholars:程贤甦)

Indexed by:

CPCI-S Scopus

Abstract:

Lignin isolated from enzymatic hydrolyzed cornstalks (EHL) is a renewable natural polymer, and rubber is one of the most important polymer materials. The application of EHL in rubber industry is of great significance. The influence of EHL and antioxidant RD on the vulcanizing characteristics, thermal oxidative aging stability under free condition, and water extraction resistance of styrene-butadiene rubber (SBR) were investigated. The effect of EHL/antioxidant D composite antioxidant on the thermal oxidative ageing of SBR was also evaluated. Results showed that the protection of SBR from thermal oxidative aging by EHL/antioxidant D composite antioxidant was superior to that of antioxidant D. This is because EHL molecules have hindered phenol group and have excellent auxiliary antioxidant role with antioxidant D. Moreover, the influence of EHL on the vulcanizing characteristics of SBR compounds was better than that of antioxidant RD, and EHL can reduce the cure rate and increase the optimum cure time. It is because that the EHL molecules have hindered phenol group and methoxy group, which can form a special structure to capture free radical and terminate the chain reaction. The retained tensile strength of SBR compounds with EHL was similar to that of the samples with antioxidant RD, while the retained elongation at break of SBR compounds with EHL was higher than that of the samples with antioxidant RD. In addition, the SBR compounds with EHL have a good water extraction resistance property, which was similar to the samples with antioxidant RD. This is because EHL have large molecular weight, good stability and low solubility in water. In conclusion, due to the low price, abundant resources, non-toxic and pollution-free, etc., EHL will have broad application prospect.

Keyword:

antioxidant lignin Styrene Butadiene rubber water-extraction resistance

Community:

  • [ 1 ] [Liu, Shusheng]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Cheng, Xiansu]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • 程贤甦

    [Cheng, Xiansu]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China

Email:

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Source :

2ND INTERNATIONAL SYMPOSIUM ON AQUA SCIENCE, WATER RESOURCE AND LOW CARBON ENERGY

ISSN: 0094-243X

Year: 2010

Volume: 1251

Page: 344-347

Language: English

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 8

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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