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author:

Xing, Yulin (Xing, Yulin.) [1] | Ku, Jiangang (Ku, Jiangang.) [2] | Fu, Weng (Fu, Weng.) [3] | Wang, Lianzhou (Wang, Lianzhou.) [4] | Chen, Huihuang (Chen, Huihuang.) [5]

Indexed by:

EI

Abstract:

Oxygen evolution reaction (OER) remains the bottleneck of many energy transformation and storage technologies due to the sluggish kinetics. Transition-metal (TM) hydroxide nanosheets with high-valent TM ions possess high intrinsic catalytic activity toward OER. Herein, by taking advantage of the inductive effect, this work presents a facile and universal strategy to fabricate atomic iridium (Ir) incorporated TM hydroxide nanosheets as highly active OER electrocatalysts. As a representative, the fabricated Ir-Ni(OH)2 (4 wt% Ir) exhibits remarkable OER performance with a low overpotential (235 mV at 10 mA cm−2), a small Tafel slope (58.4 mV dec−1), and excellent durability (60 h) in alkaline solution, significantly outperforming the benchmark IrO2 and Ni(OH)2. Mechanism studies unveil that the inductive effect between Ni and Ir endows Ni(OH)2 with high-valent Ni species, which facilitate the adsorption of nucleophilic intermediates and boost the OER activity and long-term stability of Ir-Ni(OH)2. More importantly, the reported strategy could be extended to synthesize other monometallic/bimetallic TM hydroxide nanosheets (Co, CoMn) as highly efficient OER electrocatalysts. This work should pave a universal and promising avenue to rationally design and controllably synthesize efficient yet robust OER electrocatalysts in energy-related fields. © 2020 Elsevier B.V.

Keyword:

Benchmarking Catalyst activity Cobalt alloys Electrocatalysts Electrolysis Iridium compounds Manganese alloys Nanosheets Nickel Oxygen Oxygen evolution reaction Reaction kinetics

Community:

  • [ 1 ] [Xing, Yulin]Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei; 230026, China
  • [ 2 ] [Ku, Jiangang]School of Zijin Mining, Fuzhou University, Fuzhou; 350108, China
  • [ 3 ] [Fu, Weng]School of Chemical Engineering, The University of Queensland, Brisbane; Qld; 4072, Australia
  • [ 4 ] [Wang, Lianzhou]School of Chemical Engineering, The University of Queensland, Brisbane; Qld; 4072, Australia
  • [ 5 ] [Chen, Huihuang]Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei; 230026, China

Reprint 's Address:

  • [wang, lianzhou]school of chemical engineering, the university of queensland, brisbane; qld; 4072, australia

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Source :

Chemical Engineering Journal

ISSN: 1385-8947

Year: 2020

Volume: 395

1 3 . 2 7 3

JCR@2020

1 3 . 4 0 0

JCR@2023

ESI HC Threshold:132

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 58

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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