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author:

Gómez, Andrés (Gómez, Andrés.) [1] | Wang, Qiong (Wang, Qiong.) [2] | Goñi, Alejandro R. (Goñi, Alejandro R..) [3] | Campoy-Quiles, Mariano (Campoy-Quiles, Mariano.) [5] | Abate, Antonio (Abate, Antonio.) [6]

Indexed by:

EI

Abstract:

The existence of ferroelectricity in organic-inorganic perovskite thin films has been under debate over the past few years. If proven to exist, its magnitude in comparison to other known processes occurring in perovskite, such as electronic and ionic conductivities, will determine its importance for their optoelectronic properties. In a recent paper, our group aimed at contributing to the understanding of this topic by extending the range of measurements beyond what is conventionally carried out. In particular, we employed three techniques, namely, direct piezoelectric force microscopy, piezoelectric force microscopy, and electrostatic force microscopy, which we applied to two perovskite materials, prepared with control of film thickness and grain sizes that enabled the evaluation of morphological differences. Based on our experimental data, we concluded that lead halide perovskites are ferroelectricity-free. © The Royal Society of Chemistry.

Keyword:

Electric force microscopy Electrostatic force Ferroelectricity Lead compounds Perovskite Piezoelectricity

Community:

  • [ 1 ] [Gómez, Andrés]Instituto de Ciencia de Materiales de Barcelona (ICMAB-CSIC), Campus UAB, Bellaterra; 08193, Spain
  • [ 2 ] [Wang, Qiong]Young Investigator Group Active Materials and Interfaces for Stable Perovskite Solar Cells, Helmholtz-Zentrum Berlin für Materialien und Energie, Kekuléstraße 5, Berlin; 12489, Germany
  • [ 3 ] [Goñi, Alejandro R.]Instituto de Ciencia de Materiales de Barcelona (ICMAB-CSIC), Campus UAB, Bellaterra; 08193, Spain
  • [ 4 ] [Goñi, Alejandro R.]ICREA, Passeig Lluís Companys 23, Barcelona; 08010, Spain
  • [ 5 ] [Campoy-Quiles, Mariano]Instituto de Ciencia de Materiales de Barcelona (ICMAB-CSIC), Campus UAB, Bellaterra; 08193, Spain
  • [ 6 ] [Abate, Antonio]Young Investigator Group Active Materials and Interfaces for Stable Perovskite Solar Cells, Helmholtz-Zentrum Berlin für Materialien und Energie, Kekuléstraße 5, Berlin; 12489, Germany
  • [ 7 ] [Abate, Antonio]Institute of Advanced Energy Materials, Fuzhou University, Fuzhou, Fujian; 350002, China
  • [ 8 ] [Abate, Antonio]Department of Chemical, Materials and Production Engineering, University of Naples Federico II, Piazzale Tecchio 80, Naples, Fuorigrotta; 80125, Italy

Reprint 's Address:

  • [gómez, andrés]instituto de ciencia de materiales de barcelona (icmab-csic), campus uab, bellaterra; 08193, spain

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Source :

Energy and Environmental Science

ISSN: 1754-5692

Year: 2020

Issue: 6

Volume: 13

Page: 1892-1895

3 8 . 5 3 2

JCR@2020

3 2 . 4 0 0

JCR@2023

ESI HC Threshold:159

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 11

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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