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author:

Wang, Zhihong (Wang, Zhihong.) [1] | Cao, Fenhui (Cao, Fenhui.) [2] | Chen, Kongfa (Chen, Kongfa.) [3] | Yan, Yingming (Yan, Yingming.) [4] | Chen, Yifu (Chen, Yifu.) [5] | Zhang, Yaohui (Zhang, Yaohui.) [6] | Zhu, Xingbao (Zhu, Xingbao.) [7] | Wei, Bo (Wei, Bo.) [8] | Xiong, Yueping (Xiong, Yueping.) [9] | Lv, Zhe (Lv, Zhe.) [10]

Indexed by:

EI

Abstract:

Cellular metals with the large surface/volume ratios and excellent electrical conductivity are widely applicable and have thus been studied extensively. It is highly desirable to develop a facile and cost-effective process for fabrication of porous metallic structures, and yet more so for micro/nanoporous structures. A direct-flame strategy is developed for in situ fabrication of micron-scale cellular architecture on a Ni metal precursor. The flame provides the required heat and also serves as a fuel reformer, which provides a gas mixture of H2, CO, and O2 for redox treatment of metallic Ni. The redox processes at elevated temperatures allow fast reconstruction of the metal, leading to a cellular structure on Ni wire. This process is simple and clean and avoids the use of sacrificial materials or templates. Furthermore, nanocrystalline MnO2 is coated on the microporous Ni wire (MPNW) to form a supercapacitor electrode. The MnO2/MPNW electrode and the corresponding fiber-shaped supercapacitor exhibit high specific capacitance and excellent cycling stability. Moreover, this work provides a novel strategy for the fabrication of cellular metals and alloys for a variety of applications, including catalysis, energy storage and conversion, and chemical sensing. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Keyword:

Cellular automata Chemical sensors Cost effectiveness Electrodes Energy transfer Fabrication Manganese oxide Metallurgy Nanocrystalline materials Nanocrystals Supercapacitor Transition metals Wire

Community:

  • [ 1 ] [Wang, Zhihong]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, Harbin; Heilongjiang; 150001, China
  • [ 2 ] [Cao, Fenhui]School of Mechatronic Engineering, Daqing Normal University, Daqing; Heilongjiang; 163712, China
  • [ 3 ] [Chen, Kongfa]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian; 350108, China
  • [ 4 ] [Yan, Yingming]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, Harbin; Heilongjiang; 150001, China
  • [ 5 ] [Chen, Yifu]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, Harbin; Heilongjiang; 150001, China
  • [ 6 ] [Zhang, Yaohui]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, Harbin; Heilongjiang; 150001, China
  • [ 7 ] [Zhu, Xingbao]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, Harbin; Heilongjiang; 150001, China
  • [ 8 ] [Wei, Bo]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, Harbin; Heilongjiang; 150001, China
  • [ 9 ] [Xiong, Yueping]MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, 92 West Dazhi Street, Harbin; 150001, China
  • [ 10 ] [Lv, Zhe]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, Harbin; Heilongjiang; 150001, China

Reprint 's Address:

  • [wang, zhihong]department of physics, harbin institute of technology, yikuang street 2#, harbin; heilongjiang; 150001, china

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Source :

ChemSusChem

ISSN: 1864-5631

Year: 2018

Issue: 5

Volume: 11

Page: 985-993

7 . 8 0 4

JCR@2018

7 . 5 0 0

JCR@2023

ESI HC Threshold:209

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 15

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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