Indium-Based Heterometal-Organic Frameworks with Different Nanoscale Cages: Syntheses, Structures, and Gas Adsorption Properties - Details

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Abstract：

A　series　of　rare　metal-organic　frameworks　based　on　In-M　heterometallic　clusters　[(CH3)2NH2][In3M2(BTC)4(DMF)2(H2O)4Cl2]·solvent　(1-M,　M　=　Ca,　Sr,　Ba,　H3BTC　=　1,3,5-benzenetricarboxylic　acid,　DMF　=　N,N-dimethylformamide)　have　been　successfully　synthesized.　Structural　analysis　reveals　that　1-M　represent　fascinating　three-dimensional　porous　frameworks　constructed　from　different　nanoscale　cages.　What　is　more,　these　new　materials　exhibit　interesting　gas　adsorption　properties　that　can　be　tuned　by　encapsulating　different　alkaline　earth　metal　ions.　©　2017　American　Chemical　Society.

Keyword：

Crystalline materials Dimethylformamide Gas adsorption Indium Metal ions Nanotechnology Organic solvents Organometallics

Community：

[ 1 ] [Qi, Yan-Jie]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian; 350108, China
[ 2 ] [Zhao, Dan]Fuqing Branch of Fujian Normal University, Fuqing, Fujian; 350300, China
[ 3 ] [Li, Xin-Xiong]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian; 350108, China
[ 4 ] [Ma, Xiang]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian; 350108, China
[ 5 ] [Zheng, Wen-Xu]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian; 350108, China
[ 6 ] [Zheng, Shou-Tian]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian; 350108, China

Reprint 's Address：

[li, xin-xiong]state key laboratory of photocatalysis on energy and environment, college of chemistry, fuzhou university, fuzhou, fujian; 350108, china

Email：

lxx@fzu.edu.cn

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Source ：

Crystal Growth and Design

ISSN： 1528-7483

Year： 2017

Issue： 3

Volume： 17

Page： 1159-1165

3 . 9 7 2

JCR@2017

3 . 2 0 0

JCR@2023

ESI HC Threshold：226

JCR Journal Grade：1

CAS Journal Grade：2

Cited Count：

WoS CC Cited Count： 0

SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 2

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