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author:

Xu, Cheng-Zhi (Xu, Cheng-Zhi.) [1] | Zheng, Mei-Qin (Zheng, Mei-Qin.) [2] | Chen, Keng (Chen, Keng.) [3] | Hu, Hui (Hu, Hui.) [4] (Scholars:胡晖) | Chen, Xiao-Hui (Chen, Xiao-Hui.) [5] (Scholars:陈晓晖)

Indexed by:

EI Scopus PKU CSCD

Abstract:

In this work, the impact of CeOx doping on a TiO2-SiO2 supporter on the Ag based adsorptive desulfurization for Chinese standard diesel was studied. The dispersion and valence states of Ce, Ti and Ag species were characterized, and the impact of Ce doping was investigated. The results indicated that Ce species and Ti species were dispersed evenly on the surface of SiO2 via a novel co-impregnation method. Following CeOx doping, the Ag species were in the form of oxides (about 5 nm) instead of metallic Ag particles (about 35 nm), which is due to the large amount of coordinative unsaturated sites provided by the interaction between CeOx and TiO2, as well as the oxidation-reduction property of CeOx. The Ag in the active oxide state (Ag2O2) and dispersed evenly on the supporter could interact with sulfur compounds more favorably, and therefore showed a good performance in the adsorptive desulfurization. In both static batch and dynamic breakthrough desulfurization tests, Ag-CeOx/TiO2-SiO2 was proved to be a more efficient adsorbent compared with Ag-TiO2-SiO2. It was found that the desulfurization performance of Ag-TiO2-SiO2 exhibited an excellent improvement (22.5%) after being doped with CeOx. In the static equilibrium tests, the equilibrium sulfur capacity of Ag-CeOx/TiO2-SiO2 was up to 5.38 mg/g for CN-II diesel (sulfur content 952.9 mg/kg) and the sulfur content of the CN-IV diesel (sulfur content 39.0 mg/kg) after desulfurization was less than 10 mg/kg, which could meet the CN-V standard. © 2016, Science Press. All right reserved.

Keyword:

Cerium Cerium compounds Desulfurization Diesel engines Dispersions Silica Sulfur compounds Titanium Titanium dioxide

Community:

  • [ 1 ] [Xu, Cheng-Zhi]National Engineering Research Center of Chemical Fertilizer Catalysts, Fuzhou University, Fuzhou; 350002, China
  • [ 2 ] [Xu, Cheng-Zhi]School of Chemical Engineering, Fuzhou University, Fuzhou; 350116, China
  • [ 3 ] [Zheng, Mei-Qin]National Engineering Research Center of Chemical Fertilizer Catalysts, Fuzhou University, Fuzhou; 350002, China
  • [ 4 ] [Zheng, Mei-Qin]School of Chemical Engineering, Fuzhou University, Fuzhou; 350116, China
  • [ 5 ] [Chen, Keng]National Engineering Research Center of Chemical Fertilizer Catalysts, Fuzhou University, Fuzhou; 350002, China
  • [ 6 ] [Chen, Keng]School of Chemical Engineering, Fuzhou University, Fuzhou; 350116, China
  • [ 7 ] [Hu, Hui]School of Chemical Engineering, Fuzhou University, Fuzhou; 350116, China
  • [ 8 ] [Chen, Xiao-Hui]National Engineering Research Center of Chemical Fertilizer Catalysts, Fuzhou University, Fuzhou; 350002, China
  • [ 9 ] [Chen, Xiao-Hui]School of Chemical Engineering, Fuzhou University, Fuzhou; 350116, China

Reprint 's Address:

  • 陈晓晖

    [chen, xiao-hui]school of chemical engineering, fuzhou university, fuzhou; 350116, china;;[chen, xiao-hui]national engineering research center of chemical fertilizer catalysts, fuzhou university, fuzhou; 350002, china

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Source :

Journal of Fuel Chemistry and Technology

ISSN: 0253-2409

Year: 2016

Issue: 8

Volume: 44

Page: 943-953

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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