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author:

Shao, Yan-Qun (Shao, Yan-Qun.) [1] (Scholars:邵艳群) | Yi, Zhao-Yu (Yi, Zhao-Yu.) [2] | Zhu, Jun-Qiu (Zhu, Jun-Qiu.) [3] | Lou, Chang-Ying (Lou, Chang-Ying.) [4] | Ma, Xiao-Lei (Ma, Xiao-Lei.) [5] | Tang, Dian (Tang, Dian.) [6] (Scholars:唐电)

Indexed by:

EI Scopus PKU CSCD

Abstract:

(Ir0.3Sn(0.7-x)Cex)O2 ternary oxide electrode materials (00.3Sn(0.7-x)Cex)O2 electrodes was investigated by XRD, electrochemical impedance spectroscopy (EIS) and cyclic voltammetry(CV). The results show that a certain amount of Ce can reduce the degree of crystallization of rutile phase oxide in coating, optimize the microstructure of the oxide coating, and therefore improve the capacitive properties of the electrode material. When x is 0.2, the ternary oxides electrode reaches its maximum specific capacitance of 414 F/g, which is about three times of that of the Ti/IrO2-SnO2 electrode. The electrode shows a high specific energy density, when the power density is 4.97 kW/kg, the corresponding energy density reaches 82.88 Wh/kg. When x is more than 0.3, the electronic/protonic conductivity, frequency response characteristics as well as capacitive property of the Ti/(Ir0.3Sn(0.7-x)Cex)O2 electrodes are seriously deteriorated with increasing the Ce content. Therefore, the Ce content should be controlled in less than 0.2 (mole fraction). ©, 2015, Central South University of Technology. All right reserved.

Keyword:

Cerium Cerium oxide Cyclic voltammetry Decomposition Electrochemical electrodes Electrochemical impedance spectroscopy Frequency response Microstructure Oxide minerals Protective coatings Spectroscopy Supercapacitor Titanium dioxide

Community:

  • [ 1 ] [Shao, Yan-Qun]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 2 ] [Yi, Zhao-Yu]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 3 ] [Zhu, Jun-Qiu]College of Materials Science and Engineering, Xiamen University of Technology, Xiamen; 361024, China
  • [ 4 ] [Lou, Chang-Ying]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 5 ] [Ma, Xiao-Lei]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 6 ] [Tang, Dian]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350108, China

Reprint 's Address:

  • 邵艳群

    [shao, yan-qun]college of materials science and engineering, fuzhou university, fuzhou; 350108, china

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Source :

Chinese Journal of Nonferrous Metals

ISSN: 1004-0609

CN: 43-1238/TG

Year: 2015

Issue: 3

Volume: 25

Page: 714-719

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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