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author:

Xia, Li-Na (Xia, Li-Na.) [1] | You, Jing (You, Jing.) [2] | He, Zhi-Ping (He, Zhi-Ping.) [3] | Huang, Xiao-Wei (Huang, Xiao-Wei.) [4] | Yu, Yan (Yu, Yan.) [5]

Indexed by:

EI

Abstract:

SmBaCo1.7Ni0.3O5+δ-xSm0.2Ce0.8O1.9 (SBCN-xSDC, x = 0-50 wt.%) composite cathodes were prepared and characterized for potential use in intermediate-temperature solid oxide fuel cells (IT-SOFCs) based on an SDC electrolyte. The electrical conductivity and the thermal expansion coefficient (TEC) decreased with an increase in the SDC content of SBCN-xSDC composite cathodes. TEC values decreased from 15.59 × 10-6 K-1 for SBCN to 13.17 × 10-6 K-1 for SBCN-50SDC. Furthermore, the addition of SDC to the SBCN cathode improved its electrochemical performance. Among others, the SBCN-20SDC showed the lowest polarization resistance of 0.0272 Ω cm2 at 800 °C; an anode-supported single-cell configuration of Ni-SDC/SDC/SBCN-20SDC obtained a maximum power density of 628 mW cm-2 at 800 °C. Even when the content of SDC was raised up to 50 wt.%, the electrochemical performance of SBCN-50SDC still exceeded that of pure SBCN. These results indicated that the SBCN-xSDC composite cathode is a promising material for IT-SOFCs. © 2015 Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

Keyword:

Cathodes Electrochemical properties Electrolytes Expansion Nickel Perovskite Solid oxide fuel cells (SOFC) Thermal expansion

Community:

  • [ 1 ] [Xia, Li-Na]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350116, China
  • [ 2 ] [Xia, Li-Na]Key Laboratory of Eco-Materials Advanced Technology (Fuzhou University), Fujian Province University, China
  • [ 3 ] [You, Jing]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350116, China
  • [ 4 ] [You, Jing]Key Laboratory of Eco-Materials Advanced Technology (Fuzhou University), Fujian Province University, China
  • [ 5 ] [He, Zhi-Ping]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350116, China
  • [ 6 ] [He, Zhi-Ping]Key Laboratory of Eco-Materials Advanced Technology (Fuzhou University), Fujian Province University, China
  • [ 7 ] [Huang, Xiao-Wei]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350116, China
  • [ 8 ] [Huang, Xiao-Wei]Key Laboratory of Eco-Materials Advanced Technology (Fuzhou University), Fujian Province University, China
  • [ 9 ] [Yu, Yan]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350116, China
  • [ 10 ] [Yu, Yan]Key Laboratory of Eco-Materials Advanced Technology (Fuzhou University), Fujian Province University, China

Reprint 's Address:

  • [huang, xiao-wei]key laboratory of eco-materials advanced technology (fuzhou university), fujian province university, china;;[huang, xiao-wei]college of materials science and engineering, fuzhou university, fuzhou; 350116, china

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Source :

International Journal of Hydrogen Energy

ISSN: 0360-3199

Year: 2016

Issue: 2

Volume: 41

Page: 1176-1186

3 . 5 8 2

JCR@2016

8 . 1 0 0

JCR@2023

ESI HC Threshold:177

JCR Journal Grade:1

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 15

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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