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Sealing glasses for solid oxide fuel celss must initially flow sufficiently to produce an adequate seal, then maintain enough rigidity for mechanical integrity. The thermal expansion characterization of the glass should be compatible with other SOFC components, and the glass should be chemical stable. Over 80 compositions based on modified alkaline earth silicates have been prepared and evaluated, and some general composition-property trends have been identified. The addition of B2O3 decreases the softening temperature as well as the glass transition temperature. The presence of ZnO improves the sealing condition by broadening the temperature window between glass transition and crystallization up to 230°C with high Zn content (Zn/Si molar ratio=0.7). The coefficient of thermal expansion for these 'invert glasses' depends on the average field strength of RO. The addition of BaO increases the CTE of glasses due to the low field strength of BaO. The addition of ZnO decreases the CTE of glasses due to the increase of average field strength.
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Journal of Functional Materials
ISSN: 1001-9731
CN: 50-1099/TH
Year: 2010
Issue: SUPPL. 2
Volume: 41
Page: 221-224
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SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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