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The wettability and spreading dynamics of Au-30%Si (mole fraction) alloys on graphite were studied using a modified sessile drop method under vacuum at 1373-1473 K. The results show that the wettability improves with the temperature increasing. The alloy is non-wetting with graphite and final contact angle as large as 100° at 1373 K. When T≥1393 K, the contact angle accelerates apparently with the temperature increasing, and finally presents an excellent wettability with contact angle decreasing to 16°. The formation of interfacial reaction products SiC resulting in the continuous decrease of solid-liquid interfacial energy, which provides the driving force for wetting and spreading. A spreading kinetic model is established, which explains the wetting mechanism from the angle of energy and predicts the solid-liquid interfacial energy decreasing with time in exponential relationship. The experimental results are in accord with the theoretical calculation in reaction-limited spreading. © 2016, Science Press. All right reserved.
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Chinese Journal of Nonferrous Metals
ISSN: 1004-0609
CN: 43-1238/TG
Year: 2016
Issue: 6
Volume: 26
Page: 1175-1181
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WoS CC Cited Count: 0
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ESI Highly Cited Papers on the List: 0 Unfold All
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Chinese Cited Count:
30 Days PV: 1
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