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author:

Yang, Yuan (Yang, Yuan.) [1] | Wang, Ting-Ting (Wang, Ting-Ting.) [2] | Zhu, Ding-Yi (Zhu, Ding-Yi.) [3] (Scholars:朱定一) | Ren, Yong-Bin (Ren, Yong-Bin.) [4]

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EI Scopus PKU CSCD

Abstract:

The wettability and spreading dynamics of Au-30%Si (mole fraction) alloys on graphite were studied using a modified sessile drop method under vacuum at 1373-1473 K. The results show that the wettability improves with the temperature increasing. The alloy is non-wetting with graphite and final contact angle as large as 100° at 1373 K. When T≥1393 K, the contact angle accelerates apparently with the temperature increasing, and finally presents an excellent wettability with contact angle decreasing to 16°. The formation of interfacial reaction products SiC resulting in the continuous decrease of solid-liquid interfacial energy, which provides the driving force for wetting and spreading. A spreading kinetic model is established, which explains the wetting mechanism from the angle of energy and predicts the solid-liquid interfacial energy decreasing with time in exponential relationship. The experimental results are in accord with the theoretical calculation in reaction-limited spreading. © 2016, Science Press. All right reserved.

Keyword:

Contact angle Dynamics Gold alloys Graphite Interfacial energy Silicon alloys Silicon carbide Temperature Wetting

Community:

  • [ 1 ] [Yang, Yuan]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350116, China
  • [ 2 ] [Wang, Ting-Ting]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350116, China
  • [ 3 ] [Zhu, Ding-Yi]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350116, China
  • [ 4 ] [Ren, Yong-Bin]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350116, China

Reprint 's Address:

  • 朱定一

    [zhu, ding-yi]college of materials science and engineering, fuzhou university, fuzhou; 350116, china

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Source :

Chinese Journal of Nonferrous Metals

ISSN: 1004-0609

CN: 43-1238/TG

Year: 2016

Issue: 6

Volume: 26

Page: 1175-1181

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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