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Ti/Ru0.4Sn(0.6-x)MnxO2 electrodes (x=0, 0.3, 0.6) were prepared by thermal decomposition method. The microstructure, morphology and capacitive properties of the as-prepared electrodes were investigated by XRD, SEM, CV, EIS and constant current charge-discharge. The results show that adding SnO2 into the ternary electrodes materials can inhibit the precipitation of RuO2 on surface and is beneficial to form the Ru-Mn-Sn-O solid solution oxide, and MnO2 can suppress the crystallinity of RuO2. So, the interaction of the three components lead to the decrease of the ion diffusion resistance and the improvement of the charge storage ability of Ti/Ru0.4Mn(0.6-x)SnxO2 electrodes. The maximum specific capacitance of 682 F/g is obtained for Ti/Ru0.4Mn0.3Sn0.3O2 electrode, which is about two or three times of that of Ti/RuO2-SnO2 or Ti/RuO2-MnO2 electrodes. © 2016, Central South University of Technology. All right reserved.
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Chinese Journal of Nonferrous Metals
ISSN: 1004-0609
CN: 43-1238/TG
Year: 2016
Issue: 4
Volume: 26
Page: 821-828
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 2
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