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author:

Hua, Nengbin (Hua, Nengbin.) [1] | Chen, Wenzhe (Chen, Wenzhe.) [2] | Liu, Xiaoli (Liu, Xiaoli.) [3] | Zhang, Tao (Zhang, Tao.) [4]

Indexed by:

EI

Abstract:

The non-isothermal and isothermal crystallization kinetics of Zr72.5Al10Fe17.5 glassy alloy was investigated using differential scanning calorimeter (DSC). Under non-isothermal heating condition, the primary phase in the initial crystallization is Zr6Al2Fe phase and the final crystallized products consist of Zr6Al2Fe, Zr2Fe and a-Zr phases. The apparent activation energy for crystallization estimated using the Kissinger method is 342.1 ± 8.1 kJ/mol. The local activation energy decreased with the increase in the crystallization volume fraction during nonisothermal crystallization. Under isothermal heating condition, the average Avrami exponent of about 2.76 implies a mainly diffusion-controlled three-dimensional growth with an increasing nucleation rate. The local activation energy for isothermal crystallization shows a different variation trend from that for nonisothermal crystallization, indicating different nucleation-and-growth mechanisms for the two crystallizaiton conditions. © 2016, Wuhan University of Technology and Springer-Verlag Berlin Heidelberg.

Keyword:

Activation energy Aluminum alloys Binary alloys Crystallization Crystallization kinetics Differential scanning calorimetry Glass Iron alloys Isotherms Nucleation Ternary alloys Zircaloy

Community:

  • [ 1 ] [Hua, Nengbin]Department of Materials Science and Engineering, Fuzhou University, Fuzhou; 350116, China
  • [ 2 ] [Hua, Nengbin]Department of Materials Science and Engineering, Fujian University of Technology, Fuzhou; 350118, China
  • [ 3 ] [Chen, Wenzhe]Department of Materials Science and Engineering, Fuzhou University, Fuzhou; 350116, China
  • [ 4 ] [Chen, Wenzhe]Department of Materials Science and Engineering, Fujian University of Technology, Fuzhou; 350118, China
  • [ 5 ] [Liu, Xiaoli]Department of Materials Science and Engineering, Fujian University of Technology, Fuzhou; 350118, China
  • [ 6 ] [Zhang, Tao]Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, Beijing; 100191, China

Reprint 's Address:

  • [hua, nengbin]department of materials science and engineering, fuzhou university, fuzhou; 350116, china;;[hua, nengbin]department of materials science and engineering, fujian university of technology, fuzhou; 350118, china

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Source :

Journal Wuhan University of Technology, Materials Science Edition

ISSN: 1000-2413

Year: 2016

Issue: 1

Volume: 31

Page: 191-196

0 . 4 4 7

JCR@2016

1 . 3 0 0

JCR@2023

ESI HC Threshold:324

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 4

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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