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author:

Huang, Ronglu (Huang, Ronglu.) [1] | Huang, Yangjie (Huang, Yangjie.) [2] | Lin, Xiaoxi (Lin, Xiaoxi.) [3] | Rong, Mingguang (Rong, Mingguang.) [4] | Weng, Zhiqiang (Weng, Zhiqiang.) [5]

Indexed by:

EI

Abstract:

Copper(I) fluoroalkoxide complexes bearing dinitrogen ligands were synthesized and the structure and reactivity of the complexes toward trifluoroethoxylation, pentafluoropropoxylation, and tetrafluoropropoxylation of aryl and heteroaryl bromides were investigated. Efficiency drive: A series of copper(I) fluoroalkoxide complexes bearing N,N ligands have been prepared and structurally characterized. These well-defined complexes serve as efficient reagents for the fluoroalkoxylation of aryl and heteroaryl bromides to produce a wide range of trifluoroethyl, pentafluoropropyl, and tetrafluoropropyl (hetero)aryl ethers in good to excellent yields. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keyword:

Copper Copper compounds Ligands Synthesis (chemical)

Community:

  • [ 1 ] [Huang, Ronglu]State Key Laboratory of Photocatalysis on Energy and Environment College of Chemistry, Fuzhou University, Fuzhou; 350108, China
  • [ 2 ] [Huang, Yangjie]State Key Laboratory of Photocatalysis on Energy and Environment College of Chemistry, Fuzhou University, Fuzhou; 350108, China
  • [ 3 ] [Lin, Xiaoxi]State Key Laboratory of Photocatalysis on Energy and Environment College of Chemistry, Fuzhou University, Fuzhou; 350108, China
  • [ 4 ] [Rong, Mingguang]State Key Laboratory of Photocatalysis on Energy and Environment College of Chemistry, Fuzhou University, Fuzhou; 350108, China
  • [ 5 ] [Weng, Zhiqiang]State Key Laboratory of Photocatalysis on Energy and Environment College of Chemistry, Fuzhou University, Fuzhou; 350108, China

Reprint 's Address:

  • [weng, zhiqiang]state key laboratory of photocatalysis on energy and environment college of chemistry, fuzhou university, fuzhou; 350108, china

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Source :

Angewandte Chemie - International Edition

ISSN: 1433-7851

Year: 2015

Issue: 19

Volume: 54

Page: 5736-5739

1 1 . 7 0 9

JCR@2015

1 6 . 1 0 0

JCR@2023

ESI HC Threshold:265

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 38

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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