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author:

Li, Wenliang (Li, Wenliang.) [1] | Huang, Yiyin (Huang, Yiyin.) [2] | Tang, Dian (Tang, Dian.) [3] | Zhang, Teng (Zhang, Teng.) [4] | Wang, Yaobing (Wang, Yaobing.) [5]

Indexed by:

EI

Abstract:

In this paper, RuO2-SnO2 binary oxides were prepared using a hydrothermal approach and added to Vulcan XC-72 carbon black as new support material for Pd. The X-ray diffraction, Transmission electron microscopy and X-ray photoelectronic spectra results show that the addition of binary oxides leads to the formation of (Ru,Sn)O2 solid solution in Pd/C catalyst and reduces the particle size of Pd particles due to the anchoring effect. In addition, the electrochemical CO-striping measurement reveals that the Pd/RuO2-SnO2/C catalyst exhibits the largest electrochemical active surface and the best CO tolerance. Moreover, cyclic voltammetry and chronoamperometry tests demonstrate that the Pd/RuO2-SnO2/C catalyst possesses a much higher specific activity (4.4 mA cm-2) than that of the Pd/C catalyst (3.2 mA cm-2) towards ethylene glycol electrooxidation in alkaline media, and better stability as well. These results support the suitability of Pd/RuO2-SnO2/C catalyst developed in this work as a promising candidate for direct alcohol fuel cells (DAFCs) application. ©2015 Elsevier Ltd. All rights reserved.

Keyword:

Alcohol fuels Carbon black Catalyst supports Chronoamperometry Cyclic voltammetry Direct alcohol fuel cells (DAFC) Electrooxidation Ethylene Ethylene glycol High resolution transmission electron microscopy Palladium Particle size Polyols Ruthenium compounds Solid solutions

Community:

  • [ 1 ] [Li, Wenliang]College of Materials Science and Engineering, Fuzhou University, Fujian; 350108, China
  • [ 2 ] [Huang, Yiyin]Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, Chinese Academy of Sciences, Fuzhou; 350002, China
  • [ 3 ] [Tang, Dian]College of Materials Science and Engineering, Fuzhou University, Fujian; 350108, China
  • [ 4 ] [Zhang, Teng]College of Materials Science and Engineering, Fuzhou University, Fujian; 350108, China
  • [ 5 ] [Wang, Yaobing]Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, Chinese Academy of Sciences, Fuzhou; 350002, China

Reprint 's Address:

  • [zhang, teng]college of materials science and engineering, fuzhou university, fujian; 350108, china

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Source :

Electrochimica Acta

ISSN: 0013-4686

Year: 2015

Volume: 174

Page: 178-184

4 . 8 0 3

JCR@2015

5 . 5 0 0

JCR@2023

ESI HC Threshold:265

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 22

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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