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author:

Yu, Changlin (Yu, Changlin.) [1] | Bai, Yu (Bai, Yu.) [2] | He, Hongbo (He, Hongbo.) [3] | Fan, Wenhong (Fan, Wenhong.) [4] | Zhu, Lihua (Zhu, Lihua.) [5] | Zhou, Wanqin (Zhou, Wanqin.) [6]

Indexed by:

EI PKU CSCD

Abstract:

Rod-shaped PbWO4 microcrystals of length >1 μm were fabricated by a hydrothermal route and subsequent calcination. Pt nanoparticles (NPs) of different contents (0.5 wt%, 1 wt% and 2 wt%) were subsequently deposited on the PbWO4 microcrystals, producing robust Pt/PbWO4 composite microcrystals. The PbWO4 microcrystals and Pt/PbWO4 photocatalysts were characterized by X-ray diffraction, N2 sorption measurements, scanning electron microscopy, transmission electron microscopy, and X-ray photoelectron, photoluminescence, Fourier-transform infrared, and ultraviolet-visible diffuse reflectance spectroscopies. The photocatalytic performances of the catalysts were evaluated by the consecutive photocatalytic degradation of acid orange II dye. The Pt/PbWO4 composite microcrystals exhibited high photocatalytic activity and stability. The deposition of Pt NPs produced surface plasmon resonance (SPR), which induced a large visible light absorption. A Pt NP content of 1-2 wt% resulted in an ∼2 times increase in photocatalytic activity, compared with the activity of Pt/PbWO4. The crystal structure and high crystallinity of PbWO4 resulted in its favorable photocatalytic property, and the SPR effect of the Pt NPs promoted visible light harvesting. The Pt NPs also enhanced the separation of photo-generated electrons and holes, which further promoted the photocatalytic reaction. © 2015 Dalian Institute of Chemical Physics, the Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.

Keyword:

Complexation Crystallinity Crystal structure Electrons High resolution transmission electron microscopy Image enhancement Lead compounds Light Light absorption Microcrystals Nanoparticles Photocatalytic activity Plasma stability Platinum Scanning electron microscopy Surface plasmon resonance Tungsten compounds

Community:

  • [ 1 ] [Yu, Changlin]School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi; 341000, China
  • [ 2 ] [Bai, Yu]School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi; 341000, China
  • [ 3 ] [He, Hongbo]School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi; 341000, China
  • [ 4 ] [Fan, Wenhong]Department of Environmental Science and Engineering, School of Chemistry and Environment, Beihang University, Beijing; 100191, China
  • [ 5 ] [Zhu, Lihua]School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi; 341000, China
  • [ 6 ] [Zhou, Wanqin]School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi; 341000, China
  • [ 7 ] [Zhou, Wanqin]State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, Fujian; 350002, China

Reprint 's Address:

  • [yu, changlin]school of metallurgy and chemical engineering, jiangxi university of science and technology, ganzhou, jiangxi; 341000, china

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Source :

Chinese Journal of Catalysis

ISSN: 0253-9837

CN: 21-1601/O6

Year: 2015

Issue: 12

Volume: 36

Page: 2178-2185

2 . 6 2 8

JCR@2015

1 5 . 7 0 0

JCR@2023

ESI HC Threshold:265

JCR Journal Grade:1

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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