• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

author:

Wenyuan, Liu (Wenyuan, Liu.) [1] | Cheng, Dong (Cheng, Dong.) [2] | Xiangping, Gu (Xiangping, Gu.) [3] | Liu, Yu (Liu, Yu.) [4] | Xiaoping, Qiu (Xiaoping, Qiu.) [5] | Yuchuan, Chen (Yuchuan, Chen.) [6]

Indexed by:

EI

Abstract:

Abundant kiddcreekite grains were identified in the Zijinshan Cu-Au epithermal deposit in Fujian Province, China. The mineral occurs as polycrystalline grains, 5-300 μm in size, associated with colusite, enargite, stannoidite, mawsonite, vinciennite, hemusite, tennantite and wolframite in a predominantly covellite ore. Based on electron microprobe analysis, the empirical formula of the kiddcreekite is Cu6.2Sn0.97W0.95S7.83, without significant Se or Te contents. The crystal structure of kiddcreekite was solved using the direct-space method (EPCryst) from laboratory micro X-ray diffraction (μXRD) data and refined by the Rietveld method. The R values of the final Rietveld refinement were Rp = 9.06%, Rwp = 8.31%, RB = 3.16 and RF = 2.17%. Kiddcreekite has a cubic structure, space group F43m and lattice parameter a = 10.8178(3) Å (Z = 4, V = 1265.95(6) Å3). In the unit cell, W, Sn and Cu atoms occupy the 4a, 4c and 24f Wyckoff positions, respectively, and S atoms occupy two sets of 16e Wyckoff positions. The structure of kiddcreekite consists of stacked double MeS4 layers (giving a W-Sn-Cu tier and a Cu-vacancy tier) as in the sphalerite substructure. This study also demonstrates the possibility of using laboratory μXRD data coupled with the direct-space method to solve inorganic structures in cases where samples are too small for conventional powder and single-crystal diffraction. © 2014 Mineralogical Society.

Keyword:

Binary alloys Copper alloys Copper deposits Crystal structure Deposits Electron probe microanalysis Gold alloys Gold deposits Ores Rietveld analysis Rietveld refinement Single crystals Sulfide minerals Ternary alloys Tin alloys Tungsten alloys X ray diffraction Zinc sulfide

Community:

  • [ 1 ] [Wenyuan, Liu]Chinese Academy of Geological Science, Beijing; 100037, China
  • [ 2 ] [Wenyuan, Liu]College of Zijin Mining, Fuzhou University, Fuzhou; 350108, China
  • [ 3 ] [Cheng, Dong]National Laboratory for Superconductivity, Institute of Physics, Chinese Academy of Science, Beijing; 100190, China
  • [ 4 ] [Xiangping, Gu]School of Geosciences and Info-Physics, Central South University, Changsha; 410038, China
  • [ 5 ] [Liu, Yu]College of Zijin Mining, Fuzhou University, Fuzhou; 350108, China
  • [ 6 ] [Xiaoping, Qiu]College of Zijin Mining, Fuzhou University, Fuzhou; 350108, China
  • [ 7 ] [Yuchuan, Chen]Chinese Academy of Geological Science, Beijing; 100037, China

Reprint 's Address:

Email:

Show more details

Related Keywords:

Source :

Mineralogical Magazine

ISSN: 0026-461X

Year: 2014

Issue: 7

Volume: 78

Page: 1517-1525

2 . 0 2 6

JCR@2014

2 . 8 0 0

JCR@2023

ESI HC Threshold:241

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 9

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

Affiliated Colleges:

Online/Total:76/10052855
Address:FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code:350116) Contact Us:0591-22865326
Copyright:FZU Library Technical Support:Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1