The　spherical　polyacrylonitrile　beads　were　prepared　via　phase　inversion　method　usting　DMF　as　solvent　and　dispersant　solution　as　non-solvent　and　waste　polyacrylonitrile　fibre　as　raw　material.　Then　the　spherical　PAN　beads　were　used　to　prepare　a　multifunctional　spherical　chelation　adsorbent,　denoted　as　SPDA,　under　microwave　assistant　conditions.　Besides,　the　physical　and　chemical　properties　were　also　studied.　The　results　indicated　SPDA　contained　amide　and　imidazolyl　groups.　And　the　optimum　modified　conditions　included　7:1　of　the　mass　ratio　of　monomer　and　beads,　14:100　of　the　mass　ratio　of　catalyst　and　beads,　7:5　of　the　mass　ratio　of　EG　and　beads,　640W　of　the　microwave　power　and　5mins　of　the　radiation　time.　Additionally,　study　was　also　conducted　regarding　the　adsorption　of　Cr(VI)　on　SPDA　by　static　adsorption　experiments.　The　removal　percentage　and　equilibrium　adsorption　capacity　of　SPDA　could　reach　96.2%　and　38.5mg/g　under　such　conditions　as　4　of　the　solution　pH,　120mg/L　of　Cr(VI)　concentration,　2h　of　the　adsorption　time　and　30°C　of　the　adsorption　temperature.