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author:

Xu, Ke (Xu, Ke.) [1] | Jie, Zhifu (Jie, Zhifu.) [2] | Li, Ronghua (Li, Ronghua.) [3] | Chen, Zhixin (Chen, Zhixin.) [4] | Wu, Shuting (Wu, Shuting.) [5] | Gu, Jiafang (Gu, Jiafang.) [6] | Chen, Jianzhong (Chen, Jianzhong.) [7]

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EI

Abstract:

Li[Mn1/3Co1/3Ni1/3]O2 cathode material for lithium ion batteries was coated by CaF2 via wet coating strategy. The CaF2-coated Li[Mn1/3Co1/3Ni 1/3]O2 were analyzed by X-ray diffraction spectra (XRD), the scanning electron microscope (SEM) and energy dispersive X-ray analysis (EDAX) to confirm the structure and morphology of cathode material. Cyclic voltammetry and cycling charge-discharge measurements were carried out to study the electrochemical performance of bare and coated samples, as well as the optimal coating dosage. Comparison tests have found that the capacity retention is 67.9% for bare sample and 93.5% for 1.0 wt.% CaF2-coated sample. In summary, the CaF2 coating strategy benefits the cycling performance of Li[Mn1/3Co1/3Ni1/3]O2 cathode material, and the optimal dosage of coating agent is 1.0 wt.%. © 2011 Elsevier Ltd. All rights reserved.

Keyword:

Calcium fluoride Cathodes Coated materials Coatings Cyclic voltammetry Electric discharges Energy dispersive X ray analysis Fluorine compounds Fluorspar Lithium compounds Lithium-ion batteries Morphology Scanning electron microscopy X ray diffraction analysis

Community:

  • [ 1 ] [Xu, Ke]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 2 ] [Jie, Zhifu]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 3 ] [Jie, Zhifu]Huizhou TARK-WIN Battery Co. Ltd., Guangdong 516057, China
  • [ 4 ] [Li, Ronghua]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 5 ] [Chen, Zhixin]State Kay Laboratory Breeding Base of Photocatalysis, Analysis and Test Center, Fuzhou University, Fuzhou 350002, China
  • [ 6 ] [Wu, Shuting]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 7 ] [Gu, Jiafang]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 8 ] [Chen, Jianzhong]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China

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Source :

Electrochimica Acta

ISSN: 0013-4686

Year: 2012

Volume: 60

Page: 130-133

3 . 7 7 7

JCR@2012

5 . 5 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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