The　effects　of　calcination　temperature,　time　and　additives　on　the　alkali　content　of　coal-cinder　from　the　catalytic　gasification　of　pulverized　anthracite　were　examined　by　using　the　static　calcination　method　in　a　laboratory　high　temperature　furnace　in　this　study.　The　results　indicated　that　the　optimum　calcination　temperature　and　time　were　respectively　870°C　and　30　min,　and　the　optimum　dealkalization　additive　is　kaolinite.　By　adding　only　5%　kaolinite　in　the　calcination　process,　the　dealkalization　rate　could　be　increased　to　100%.　Most　importantly,　with　analyzing　the　calcined　cinder　by　X-ray　powder　diffraction　(XRD)　and　scanning　electron　microscope　(SEM),　it　was　clear　that　at　an　appropriate　calcination　temperature,　the　activated　SiO2　and　Al2O3　in　alkaline　coal-cinder　would　react　with　the　decomposed　fused　Na2CO3　to　form　a　new　neutral　matter　nepheline　(NaAlSiO4)　and　other　amorphous　silicate　compounds,　causing　an　obvious　reduction　of　the　alkali　content　in　coal-cinder.