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author:

Xu, Xiaoping (Xu, Xiaoping.) [1] (Scholars:许小平) | Huther, Andreas (Huther, Andreas.) [2] | Maurer, Gerd (Maurer, Gerd.) [3]

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Abstract:

N-isopropylacrylamide (NIPAAm) was used to synthesize NIPAAm homopolymer (nonionized) and NIPAAm-sodium methacrylate copolymer (ionized). The swelling equilibria for both gels were obtained in aqueous solution of ethanol with concentration ranging from 0 to 100% (by mass) at 25°C. The swollen gel in water shrank first with the addition of a small amount of ethanol and then reswelled with further addition of ethanol showing not only a discontinuous volume phase transition but also a typical reentrant phenomenon. A thermodynamic model based on the UNIQUAC with the free-volume contribution was applied to correlate and predict the swelling behavior of the poly(NIPAAM)-gels in ethanol-water mixture.

Keyword:

Copolymers Ethanol Homopolymerization Hydrogels Phase transitions Solutions Swelling

Community:

  • [ 1 ] [Xu, Xiaoping]Dept. of Chem. Eng., Fuzhou Univ., Fuzhou 350002, China
  • [ 2 ] [Huther, Andreas]Lehrstuhl fur Tech. Thermodynamik, Univ. Kaiserslautern, Kaiserslautern 67663, Germany
  • [ 3 ] [Maurer, Gerd]Lehrstuhl fur Tech. Thermodynamik, Univ. Kaiserslautern, Kaiserslautern 67663, Germany

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Source :

Chinese Journal of Chemical Engineering

ISSN: 1004-9541

CN: 11-3270/TQ

Year: 2003

Issue: 3

Volume: 11

Page: 264-268

0 . 3 5 7

JCR@2003

3 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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