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Abstract:
N-isopropylacrylamide (NIPAAm) was used to synthesize NIPAAm homopolymer (nonionized) and NIPAAm-sodium methacrylate copolymer (ionized). The swelling equilibria for both gels were obtained in aqueous solution of ethanol with concentration ranging from 0 to 100% (by mass) at 25°C. The swollen gel in water shrank first with the addition of a small amount of ethanol and then reswelled with further addition of ethanol showing not only a discontinuous volume phase transition but also a typical reentrant phenomenon. A thermodynamic model based on the UNIQUAC with the free-volume contribution was applied to correlate and predict the swelling behavior of the poly(NIPAAM)-gels in ethanol-water mixture.
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Chinese Journal of Chemical Engineering
ISSN: 1004-9541
CN: 11-3270/TQ
Year: 2003
Issue: 3
Volume: 11
Page: 264-268
0 . 3 5 7
JCR@2003
3 . 7 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
JCR Journal Grade:3
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 0
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