Hydrothermal synthesis and crystal structure of a novel polyoxometalate K(C 4 N 2 H 12 ) 4 (C 4 N 2 H 11 ) 2 -[Mo V 8 Mo VI 4 CdP 8 O 54 (OH) 8 ] F·6H 2 O - Details

author：

Indexed by：

Scopus CSCD

Abstract：

The　title　compound　1　has　been　synthesized　by　the　reaction　of　H　2　MoO　4　,　CdCl　2　,　H　3　PO　4　,　KF,　piperazine　hexahydrate　and　water　in　aqueous　solution　under　mild　hydrothermal　conditions.　Single-crystal　X-ray　analysis　reveals　that　the　title　compound　crystallizes　in　the　triclinic　system,　space　group　P1̄　with　a　=　14.049(3),　b　=　15.972(3),　c　=　20.043(4)　Å,　α　=　85.82(3),　β　-　81.28(3),　γ　=　67.15(3)°,　V=　4095.9(14)　Å　3　,　M　r　=　3204.62,　Z=　2,　D　c　=　2.598　g/cm　3　,　μ　=　2.360　mm　-1　,　F(000)　=　3124,　the　final　R　=　0.0314,　wR　=　0.0826　and　S　=　0.989　for　18592　observed　reflections　with　I　>　2σ(I).　The　crystal　packing　is　stabilized　by　N-H...O　and　O-H...O　intra-and　intermolecular　hydrogen　bonds　to　form　an　infinite　3D　network.

Keyword：

Crystal structure; Hydrothermal synthesis; Polyoxometalate

Community：

[ 1 ] [Chen, W.-H.]College of Chemistry and Material Science, Longyan University, Longyan, Fujian 364000, China
[ 2 ] Yuri-Long Zhou, College of Chemistry and Material Science, Longyan University, Longyan, Fujian 364000, China, Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
[ 3 ] Yuri-Long Zhou, College of Chemistry and Material Science, Longyan University, Longyan, Fujian 364000, China, Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
[ 4 ] [Ta, H.-G.]College of Chemistry and Material Science, Longyan University, Longyan, Fujian 364000, China
[ 5 ] [Hu, Z.-B.]College of Chemistry and Material Science, Longyan University, Longyan, Fujian 364000, China
[ 6 ] [Zhang, Z.-S.]College of Chemistry and Material Science, Longyan University, Longyan, Fujian 364000, China
[ 7 ] [Qiu, Z.-H.]College of Chemistry and Material Science, Longyan University, Longyan, Fujian 364000, China
[ 8 ] [Zhang, L.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
[ 9 ] [Zeng, Q.-X.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China

Reprint 's Address：

[Chen, W.-H.]College of Chemistry and Material Science, Longyan University, Longyan, Fujian 364000, China

Email：

cwh_2125@163.com

Show more details

Related Keywords：

Source ：

Jiegou Huaxue

ISSN： 0254-5861

CN： 35-1112/TQ

Year： 2009

Issue： 12

Volume： 28

Page： 1677-1680

0 . 5 4 4

JCR@2009

5 . 9 0 0

JCR@2023

ESI Discipline： CHEMISTRY;

JCR Journal Grade：4

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 1

Affiliated Colleges：

化学学院本学院/部未明确归属的数据

Get Fulltext

Library Discovery Baidu Scholar Search SCOPUS

Type
Departments

All Years Choose Year From to