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author:

Zhang, J. (Zhang, J..) [1] | Huang, Y. (Huang, Y..) [2] | Chen, X. (Chen, X..) [3] | Chen, J. (Chen, J..) [4] | Li, H. (Li, H..) [5] | Chen, G. (Chen, G..) [6] (Scholars:陈国南)

Indexed by:

Scopus PKU CSCD

Abstract:

A simple, rapid and effective method, the dispersive liquid-liquid microextraction coupled with high performance liquid chromatography-fluorescence detection (DLLME-HPLCFLD), has been developed for the extraction and determination of polynuclear aromatic hydrocarbons (PAHs) in environmental water samples. The factors relevant to the microextraction efficiency, such as type and volume of dispersion agent and extraction solvents and the extraction time were investigated and optimized. Under the optimized extraction conditions, the reliability of the proposed method was evaluated. The linear response of this method was in the range of 0. 01 -10 μg/L (r ≥ 0. 991 3), the relative standard deviations (RSDs) of peak area for 0. 05 μg/L PAHs were in the range of 2. 3% - 4. 7% (n = 6). At room temperature; the method exhibited excellent enrichment factors and good recoveries, 674 - 1 032 and 67. 4% - 103. 2% respectively. The detection limits (S/N = 3) were in the range of 0. 000 3-0. 002 μg/L. The developed method was applied to the determination of 15 PAHs in the water from Aojiang river, the average recoveries were 79. 5% - 92. 3% with RSD of 4. 3% - 6. 7% (n =5). The developed method is suitable for the analysis of trace PAHs in environmental water samples.

Keyword:

Dispersive liquid-liquid microextraction; Environmental water samples; High performance liquid chromatography (HPLC); Polynuclear aromatic hydrocarbons

Community:

  • [ 1 ] [Zhang, J.]Ministry of Education Key Laboratory of Analysis, Detection Technology for Food Safety, Department of Chemistry, Fuzhou University, Fuzhou 350002, China
  • [ 2 ] [Zhang, J.]Fujian Environmental Monitoring Center, Fuzhou 350003, China
  • [ 3 ] [Huang, Y.]College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350108, China
  • [ 4 ] [Chen, X.]Fujian Environmental Monitoring Center, Fuzhou 350003, China
  • [ 5 ] [Chen, J.]Fujian Environmental Monitoring Center, Fuzhou 350003, China
  • [ 6 ] [Li, H.]College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350108, China
  • [ 7 ] [Chen, G.]Ministry of Education Key Laboratory of Analysis, Detection Technology for Food Safety, Department of Chemistry, Fuzhou University, Fuzhou 350002, China

Reprint 's Address:

  • 陈国南

    [Chen, G.]Ministry of Education Key Laboratory of Analysis, Detection Technology for Food Safety, Department of Chemistry, Fuzhou University, Fuzhou 350002, China

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Source :

Chinese Journal of Chromatography (Se Pu)

ISSN: 1000-8713

CN: 21-1185/O6

Year: 2009

Issue: 6

Volume: 27

Page: 799-803

1 . 2 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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