The　mass　transfer　of　phenol　from　feed　phase　into　stripping　phase　through　supported　liquid　membrane　(SLM)　was　studied　by　using　Celgard2500　porous　polypropylene　flat-sheet　membranes　as　supports　and　tributyl　phosphate　(TBP)　dissolved　in　kerosene　as　carrier.　The　composition　mole　fraction　of　phenol　complex　in　TBP/kerosene　system　was　1:1　through　the　determination　of　traditional　extraction　methods,　and　the　value　of　extraction　equilibrium　constants　was　96.72　at　25.0°C.　The　effects　of　pH　value,　initial　mass　the　concentration　in　feed　phase,　stirring　speed　of　the　feed　and　stripping　phases,　the　concentration　of　TBP　in　the　membrane　and　the　sodium　hydroxide　concentration　in　the　stripping　phase　on　the　mass　transfer　rate　of　phenol　were　also　investigated.　The　optimal　conditions　of　separating　phenol　through　SLM　are　as　follows:　the　pH　value　of　feed　phase　is　below　9,　the　phenol　initial　mass　concentration　in　feed　phase　is　below　1000　mg/L,　the　stirring　speed　of　the　feed　and　stripping　phases　is　more　than　300　r/min,　the　concentration　of　TBP　in　the　membrane　is　0.55　mol/L,　and　the　sodium　hydroxide　concentration　in　the　stripping　phase　is　0.10　mol/L.　The　mass　transfer　kinetic　equation　was　determined　in　terms　of　double-film　theory.　Various　parameters　such　as　permeability　coefficient,　thickness　of　aqueous　diffusion　layer　and　diffusion　coefficient　of　phenol　through　SLM　were　evaluated　by　the　linear　slope　method.　The　calculated　results　agree　well　with　the　experimental　data　according　to　the　kinetic　equation　and　the　deviation　between　them　is　within　2%.