A low-dimensional viologen/iodoargentate hybrid [(BV)2(Ag 5I9)]n: Structure, properties, and theoretical study - Details

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Abstract：

A　new　low-dimensional　benzyl　viologen/iodoargentate　hybrid,　[(BV)　2(Ag5I9)]n　(1)　(BV2+　=　benzyl　viologen)　was　prepared.　In　1,　(Ag6I9)　n2-　chain　exhibits　a　new　type　of　one-dimensional　chain　constructed　from　vertex-sharing　of　Ag5I10　units,　and　its　two-dimensional　layer　structure　was　constructed　from　C-　H···I　hydrogen　bonds.　Strong　luminescence　at　404　nm　can　be　detected　in　1.　DFT　calculation　suggests　that　1　displays　a　reduced　bandgap,　which　is　led　by　a　more　dispersed　LUMO　band　of　BV2+　compared　with　MV　2+　in　[MV(Ag2I4)]n.　Copyright　©　2014　WILEY-VCH　Verlag　GmbH　&　Co.　KGaA,　Weinheim.

Keyword：

Benzyl viologen; DFT calculation; Iodoargentate; Organic-inorganic hybrid

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[ 1 ] [Chen, Q.-Y.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian, 350108, China
[ 2 ] [Cheng, X.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian, 350108, China
[ 3 ] [Wang, T.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian, 350108, China
[ 4 ] [Yu, Z.-H.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian, 350108, China
[ 5 ] [Zhang, C.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian, 350108, China
[ 6 ] [Lin, S.-K.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian, 350108, China
[ 7 ] [Li, H.-H.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian, 350108, China
[ 8 ] [Chen, Z.-R.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian, 350108, China

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Zeitschrift fur Anorganische und Allgemeine Chemie

ISSN： 0044-2313

Year： 2014

Issue： 2

Volume： 640

Page： 439-443

1 . 1 6

JCR@2014

1 . 1 0 0

JCR@2023

ESI Discipline： CHEMISTRY;

ESI HC Threshold：268

JCR Journal Grade：3

CAS Journal Grade：4

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count： 22

ESI Highly Cited Papers on the List： 0 Unfold All

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Chinese Cited Count：

30 Days PV： 5

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