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author:

Zheng, O. (Zheng, O..) [1] | Yan, H. (Yan, H..) [2] | Long, Y. (Long, Y..) [3] | Zhao, J. (Zhao, J..) [4] | Gao, S. (Gao, S..) [5]

Indexed by:

Scopus SCIE PKU CSCD

Abstract:

With n-hexanol as the cosurfactant, quaternary ammonium Gemini surfactants C12-EOx-C12 · 2Br (x = 1, 2, 3) formed the reverse micelles in n-heptane. The critical reverse micelle concentrations (cmch) were determined using the absorption spectrum method with iodine as the probe. All values were less than the corresponding critical micelle concentration (cmcaq) in aqueous solution, where C12-EOx-C12 · 2Br formed the normal micelles. The cmch increased with increasing x, which was similar to the variation of cmcaq with x. The saturated amount of water solubilizated by the reverse micelles was enhanced by either increasing x or raising the temperature. © 2007 Chinese Chemical Society and College of Chemistry and Molecular Engineering, Peking University.

Keyword:

n-hexanol/n-heptane solution; Quaternary ammonium Gemini surfactants; Reverse micelle; Solubilizing water

Community:

  • [ 1 ] [Zheng, O.]Department of Applied Chemistry, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, 350002, China
  • [ 2 ] [Yan, H.]Department of Applied Chemistry, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, 350002, China
  • [ 3 ] [Long, Y.]Department of Applied Chemistry, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, 350002, China
  • [ 4 ] [Zhao, J.]Department of Applied Chemistry, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, 350002, China
  • [ 5 ] [Gao, S.]Department of Applied Chemistry, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, 350002, China

Reprint 's Address:

  • [Zhao, J.]Department of Applied Chemistry, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, 350002, China

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Source :

Acta Physico - Chimica Sinica

ISSN: 1872-1508

Year: 2007

Issue: 1

Volume: 23

Page: 64-67

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 3

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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