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author:

Zheng Ou (Zheng Ou.) [1] (Scholars:郑欧) | Yan Hua (Yan Hua.) [2] | Long Yun-Xia (Long Yun-Xia.) [3] | Zhao Jian-Xi (Zhao Jian-Xi.) [4] (Scholars:赵剑曦) | Gao Shao-Kang (Gao Shao-Kang.) [5] (Scholars:高绍康)

Indexed by:

Scopus SCIE PKU CSCD

Abstract:

With n-hexanol as cosurfactant, quaternary ammonium Gemini surfactants C-12 center dot EOx-C-12 center dot 2Br (x = 1,2,3) formed reverse micelles in n-heptane. The critical reverse micelle concentrations (cmc(h)) were determined using the absorption spectrum method with iodine as the probe. All values were lesser than the corresponding critical micelle concentration (cmc(aq)) in aqueous solution, where C-12-EOx-C-12 center dot 2Br formed the normal micelles. The cmc(h) increased with increasing x, which was similar to the variation of cmc(aq) with x. The saturated amount of water solubilizated by the reverse micelles was enhanced by either increasing x or by raising the temperature.

Keyword:

n-hexanol/n-heptane solution quaternary ammonium Gemini surfactants reverse micelle solubilizing water

Community:

  • [ 1 ] Fuzhou Univ, Coll Chem & Chem Engn, Dept Appl Chem, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 赵剑曦

    [Zhao Jian-Xi]Fuzhou Univ, Coll Chem & Chem Engn, Dept Appl Chem, Fuzhou 350002, Peoples R China

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Source :

ACTA PHYSICO-CHIMICA SINICA

ISSN: 1000-6818

CN: 11-1892/O6

Year: 2007

Issue: 1

Volume: 23

Page: 64-67

0 . 6 1 1

JCR@2007

1 0 . 8 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:4

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 3

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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