Metal　halide　perovskites　with　direct　band　gap　and　strong　light　absorption　are　promising　materials　for　harvesting　solar　energy;　however,　their　relatively　narrow　band　gap　limits　their　redox　ability　when　used　as　a　photocatalyst.　Adding　a　second　semiconductor　component　with　the　appropriate　band　structure　offsets　can　generate　a　Z-scheme　photocatalytic　system,　taking　full　advantage　of　the　perovskite＇s　intrinsic　properties.　In　this　work,　we　develop　a　direct　Z-scheme　photocatalyst　based　on　formamidinium　lead　bromide　and　bismuth　tungstate　(FAPbBr(3)/Bi2WO6)　with　strong　redox　ability　for　artificial　solar-to-chemical　energy　conversion.　With　desirable　band　offsets　and　strong　joint　redox　potential,　the　dual　photocatalyst　is　shown　to　form　a　semicoherent　heterointerface.　Ultrafast　transient　infrared　absorption　studies　employing　selective　excitation　reveal　synergetic　photocarrier　dynamics　and　demonstrate　Z-scheme　charge　transfer　mechanisms.　Under　simulated　solar　irradiation,　a　large　driving　force　photoredox　reaction　(similar　to　2.57　eV)　of　CO2　reduction　coupled　with　benzyl　alcohol　oxidation　to　benzaldehyde　is　achieved　on　the　Z-scheme　FAPbBr(3)/Bi2WO6　photocatalyst,　harnessing　the　full　synergetic　potential　of　the　combined　system.