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author:

Lin, Guiyun (Lin, Guiyun.) [1] | Sun, Long (Sun, Long.) [2] | Huang, Guocheng (Huang, Guocheng.) [3] (Scholars:黄国城) | Chen, Qiaoshan (Chen, Qiaoshan.) [4] (Scholars:陈巧珊) | Fang, Shengqiong (Fang, Shengqiong.) [5] (Scholars:方圣琼) | Bi, Jinhong (Bi, Jinhong.) [6] (Scholars:毕进红) | Wu, Ling (Wu, Ling.) [7] (Scholars:吴棱)

Indexed by:

EI SCIE

Abstract:

Photocatalytic conversion of CO2 into value-added chemical fuels with visible light provides a green method to relieve the challenges of the energy crisis and environmental problems. Developing highly efficient photocatalysts is essential to achieve this technology. Herein, we designed and successfully synthesized copper cobaltite/covalent triazine-based framework (CuCo2O4/CTF-1) Z-scheme heterojunction catalysts for photocatalytic CO2 reduction. The obtained CuCo2O4/CTF-1 composites exhibited enhanced photocatalytic CO production activity. The optimal properties were 12.7-fold and 11.6-fold higher than those of pure CTF-1 and CuCo2O4, respectively. According to the analysis of UV-vis diffuse reflectance spectra, CO2 uptake isotherms, electrochemical impedance spectroscopy and transient photocurrent responses, the enhanced photocatalytic CO production performance of CuCo2O4/CTF-1 composites can be ascribed to its enhanced visible light absorption and CO2 adsorption capability, increased spatial separation of photoinduced charge carriers, and optimized redox ability resulting from the direct Z-scheme CuCo2O4/CTF-1 heterojunction. This work offers a novel strategy for designing and constructing CTF-based direct Z-scheme heterojunction photocatalysts for photocatalytic CO2 conversion to chemical energy fuels.

Keyword:

Community:

  • [ 1 ] [Lin, Guiyun]Fuzhou Univ, Dept Environm Sci & Engn, Minhou 350108, Fujian, Peoples R China
  • [ 2 ] [Sun, Long]Fuzhou Univ, Dept Environm Sci & Engn, Minhou 350108, Fujian, Peoples R China
  • [ 3 ] [Huang, Guocheng]Fuzhou Univ, Dept Environm Sci & Engn, Minhou 350108, Fujian, Peoples R China
  • [ 4 ] [Chen, Qiaoshan]Fuzhou Univ, Dept Environm Sci & Engn, Minhou 350108, Fujian, Peoples R China
  • [ 5 ] [Fang, Shengqiong]Fuzhou Univ, Dept Environm Sci & Engn, Minhou 350108, Fujian, Peoples R China
  • [ 6 ] [Bi, Jinhong]Fuzhou Univ, Dept Environm Sci & Engn, Minhou 350108, Fujian, Peoples R China
  • [ 7 ] [Bi, Jinhong]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Minhou 350108, Fujian, Peoples R China
  • [ 8 ] [Wu, Ling]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Minhou 350108, Fujian, Peoples R China

Reprint 's Address:

  • 方圣琼 毕进红

    [Fang, Shengqiong]Fuzhou Univ, Dept Environm Sci & Engn, Minhou 350108, Fujian, Peoples R China;;[Bi, Jinhong]Fuzhou Univ, Dept Environm Sci & Engn, Minhou 350108, Fujian, Peoples R China;;[Bi, Jinhong]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Minhou 350108, Fujian, Peoples R China

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Source :

SUSTAINABLE ENERGY & FUELS

ISSN: 2398-4902

Year: 2021

Issue: 3

Volume: 5

Page: 732-739

6 . 8 1 3

JCR@2021

5 . 0 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:142

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 22

SCOPUS Cited Count: 22

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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