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author:

Kang, Biyu (Kang, Biyu.) [1] | Wang, Yiyi (Wang, Yiyi.) [2] | He, Xiaotong (He, Xiaotong.) [3] | Wu, Yaling (Wu, Yaling.) [4] | Li, Xinye (Li, Xinye.) [5] | Lin, Chuyuan (Lin, Chuyuan.) [6] | Chen, Qinghua (Chen, Qinghua.) [7] | Zeng, Lingxing (Zeng, Lingxing.) [8] | Wei, Mingdeng (Wei, Mingdeng.) [9] (Scholars:魏明灯) | Qian, Qingrong (Qian, Qingrong.) [10]

Indexed by:

EI SCIE

Abstract:

Sodium-ion batteries (SIBs) have been regarded as a promising substitute for lithium-ion batteries but there are still formidable challenges in developing an anode material with adequate lifespan and outstanding rate performance. Transition metal dichalcogenides (TMDs) are promising anode materials for SIBs due to their high theoretical capacities. However, their severe volume expansions and low electronic conductivity impede their practical developments. In addition, the synthesis of energy storage materials from waste biomass has aroused extensive attention. Herein, we synthesize WS2 nanocrystals embedded in N and P co-doped biochar via a facile bio-sorption followed by sulphurization, employing waste chlorella as the adsorbent and bio-reactor. The WS2 nanocrystals are beneficial for storing more sodium ions and expediting the transportation of sodium ions, thus improving the capacity and reaction kinetics. Chlorella acts as a reactor and not only inhibits the stacking of WS2 nanocrystals during the synthesis process but also alleviates the mechanical pressure of composite during the charge/discharge process. As a result, the WS2/NPC-2 electrode delivers a high specific capacity (436 mA h g(-1) at 0.1 A g(-1)) and superior rate performance of 311 mA h g(-1) at 3 A g(-1) for SIBs. It also exhibits excellent stability even up to 6000 cycles at 5 A g(-1), which is one of the optimal long-cycle properties reported for WS2-based materials to date.

Keyword:

Community:

  • [ 1 ] [Kang, Biyu]Fujian Normal Univ, Coll Environm Sci & Engn, Engn Res Ctr Polymer Green Recycling, Minist Educ, Fuzhou 350007, Fujian, Peoples R China
  • [ 2 ] [Wang, Yiyi]Fujian Normal Univ, Coll Environm Sci & Engn, Engn Res Ctr Polymer Green Recycling, Minist Educ, Fuzhou 350007, Fujian, Peoples R China
  • [ 3 ] [He, Xiaotong]Fujian Normal Univ, Coll Environm Sci & Engn, Engn Res Ctr Polymer Green Recycling, Minist Educ, Fuzhou 350007, Fujian, Peoples R China
  • [ 4 ] [Li, Xinye]Fujian Normal Univ, Coll Environm Sci & Engn, Engn Res Ctr Polymer Green Recycling, Minist Educ, Fuzhou 350007, Fujian, Peoples R China
  • [ 5 ] [Lin, Chuyuan]Fujian Normal Univ, Coll Environm Sci & Engn, Engn Res Ctr Polymer Green Recycling, Minist Educ, Fuzhou 350007, Fujian, Peoples R China
  • [ 6 ] [Chen, Qinghua]Fujian Normal Univ, Coll Environm Sci & Engn, Engn Res Ctr Polymer Green Recycling, Minist Educ, Fuzhou 350007, Fujian, Peoples R China
  • [ 7 ] [Zeng, Lingxing]Fujian Normal Univ, Coll Environm Sci & Engn, Engn Res Ctr Polymer Green Recycling, Minist Educ, Fuzhou 350007, Fujian, Peoples R China
  • [ 8 ] [Qian, Qingrong]Fujian Normal Univ, Coll Environm Sci & Engn, Engn Res Ctr Polymer Green Recycling, Minist Educ, Fuzhou 350007, Fujian, Peoples R China
  • [ 9 ] [Wu, Yaling]Fujian Normal Univ, Biomed Res Ctr South China, Fujian Key Lab Innate Immune Biol, Fuzhou 350007, Fujian, Peoples R China
  • [ 10 ] [Wu, Yaling]Fujian Normal Univ, Coll Life Sci, Fuzhou 350007, Fujian, Peoples R China
  • [ 11 ] [Zeng, Lingxing]Fujian Key Lab Pollut Control & Resource Reuse, Fuzhou 350007, Fujian, Peoples R China
  • [ 12 ] [Qian, Qingrong]Fujian Key Lab Pollut Control & Resource Reuse, Fuzhou 350007, Fujian, Peoples R China
  • [ 13 ] [Zeng, Lingxing]Nankai Univ, Coll Chem, Key Lab Adv Energy Mat Chem, Minist Educ, Tianjin 300071, Peoples R China
  • [ 14 ] [Qian, Qingrong]Nankai Univ, Coll Chem, Key Lab Adv Energy Mat Chem, Minist Educ, Tianjin 300071, Peoples R China
  • [ 15 ] [Wei, Mingdeng]Fuzhou Univ, Fujian Prov Key Lab Electrochem Energy Storage Ma, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address:

  • [Zeng, Lingxing]Fujian Normal Univ, Coll Environm Sci & Engn, Engn Res Ctr Polymer Green Recycling, Minist Educ, Fuzhou 350007, Fujian, Peoples R China;;[Wu, Yaling]Fujian Normal Univ, Biomed Res Ctr South China, Fujian Key Lab Innate Immune Biol, Fuzhou 350007, Fujian, Peoples R China;;[Wu, Yaling]Fujian Normal Univ, Coll Life Sci, Fuzhou 350007, Fujian, Peoples R China;;[Zeng, Lingxing]Fujian Key Lab Pollut Control & Resource Reuse, Fuzhou 350007, Fujian, Peoples R China;;[Zeng, Lingxing]Nankai Univ, Coll Chem, Key Lab Adv Energy Mat Chem, Minist Educ, Tianjin 300071, Peoples R China

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Source :

DALTON TRANSACTIONS

ISSN: 1477-9226

Year: 2021

Issue: 41

Volume: 50

Page: 14745-14752

4 . 5 6 9

JCR@2021

3 . 5 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:117

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 8

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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