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Abstract:
High-frequency responsive electrochemical capacitor (EC), as an ideal lightweight filtering capacitor, can directly convert alternating current (AC) to direct current (DC). However, current electrodes are stuck in limited electrode area and tortuous ion transport. Herein, strictly vertical graphene arrays (SVGAs) prepared by electric-field-assisted plasma enhanced chemical vapour deposition have been successfully designed as the main electrode to ensure ions rapidly adsorb/desorb in richly available graphene surface. SVGAs exhibit an outstanding specific areal capacitance of 1.72 mF cm(-2) at phi(120)=80.6 degrees even after 500 000 cycles, which is far better than that of most carbon-related materials. Impressively, the output voltage could also be improved to 2.5 V when using organic electrolyte. An ultra-high energy density of 0.33 mu Wh cm(-2) can also be handily achieved. Moreover, ECs-SVGAs can well smooth arbitrary AC waveforms into DC signals, exhibiting excellent filtering performance.
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Source :
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN: 1433-7851
Year: 2021
Issue: 46
Volume: 60
Page: 24505-24509
1 6 . 8 2 3
JCR@2021
1 6 . 1 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:117
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 17
SCOPUS Cited Count: 16
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 0
Affiliated Colleges: