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author:

Wei, Ping (Wei, Ping.) [1] | Cheng, Yong (Cheng, Yong.) [2] | Yan, Xiaolin (Yan, Xiaolin.) [3] | Ye, Weibin (Ye, Weibin.) [4] | Lan, Xiangna (Lan, Xiangna.) [5] | Wang, Lina (Wang, Lina.) [6] | Sun, Jingjie (Sun, Jingjie.) [7] | Yu, Zhiyang (Yu, Zhiyang.) [8] (Scholars:喻志阳) | Luo, Guangfu (Luo, Guangfu.) [9] | Yang, Yong (Yang, Yong.) [10] | Rummeli, Mark H. (Rummeli, Mark H..) [11] | Wang, Ming-Sheng (Wang, Ming-Sheng.) [12]

Indexed by:

EI SCIE

Abstract:

Encapsulation of lithium in the confined spaces within individual nanocapsules is intriguing and highly desirable for developing high-performance Li metal anodes. This work aims for a mechanistic understanding of Li encapsulation and its confined growth kinetics inside 1D enclosed spaces. To achieve this, amorphous carbon nanotubes are employed as a model host using in situ transmission electron microscopy. The carbon shells have dual roles, providing geometric/mechanical constraints and electron/ion transport channels, which profoundly alter the Li growth patterns. Li growth/dissolution takes place via atom addition/removal at the free surfaces through Li+ diffusion along the shells in the electric field direction, resulting in the formation of unusual Li structures, such as poly-crystalline nanowires and free-standing 2D ultrathin (1-2 nm) Li membranes. Such confined front-growth processes are dominated by Li {110} or {200} growing faces, distinct from the root growth of single-crystal Li dendrites outside the nanotubes. Controlled experiments show that high lithiophilicity/permeability, enabled by sufficient nitrogen/oxygen doping or pre-lithiation, is critical for the stable encapsulation of lithium inside carbonaceous nanocapsules. First-principles-based calculations reveal that N/O doping can reduce the diffusion barrier for Li+ penetration, and facilitate Li filling driven by energy minimization associated with the formation of low-energy Li/C interfaces.

Keyword:

2D Li crystals amorphous carbon nanotubes in situ TEM Li encapsulation lithium metal anodes spatially confined growth

Community:

  • [ 1 ] [Wei, Ping]Xiamen Univ, Coll Chem & Chem Engn, Coll Mat, State Key Lab Phys Chem Solid Surfaces Coll Mat, Xiamen 361005, Peoples R China
  • [ 2 ] [Cheng, Yong]Xiamen Univ, Coll Chem & Chem Engn, Coll Mat, State Key Lab Phys Chem Solid Surfaces Coll Mat, Xiamen 361005, Peoples R China
  • [ 3 ] [Yan, Xiaolin]Xiamen Univ, Coll Chem & Chem Engn, Coll Mat, State Key Lab Phys Chem Solid Surfaces Coll Mat, Xiamen 361005, Peoples R China
  • [ 4 ] [Ye, Weibin]Xiamen Univ, Coll Chem & Chem Engn, Coll Mat, State Key Lab Phys Chem Solid Surfaces Coll Mat, Xiamen 361005, Peoples R China
  • [ 5 ] [Lan, Xiangna]Xiamen Univ, Coll Chem & Chem Engn, Coll Mat, State Key Lab Phys Chem Solid Surfaces Coll Mat, Xiamen 361005, Peoples R China
  • [ 6 ] [Sun, Jingjie]Xiamen Univ, Coll Chem & Chem Engn, Coll Mat, State Key Lab Phys Chem Solid Surfaces Coll Mat, Xiamen 361005, Peoples R China
  • [ 7 ] [Yang, Yong]Xiamen Univ, Coll Chem & Chem Engn, Coll Mat, State Key Lab Phys Chem Solid Surfaces Coll Mat, Xiamen 361005, Peoples R China
  • [ 8 ] [Wang, Ming-Sheng]Xiamen Univ, Coll Chem & Chem Engn, Coll Mat, State Key Lab Phys Chem Solid Surfaces Coll Mat, Xiamen 361005, Peoples R China
  • [ 9 ] [Wang, Lina]Southern Univ Sci & Technol, Dept Mat Sci & Engn, Shenzhen 518055, Peoples R China
  • [ 10 ] [Luo, Guangfu]Southern Univ Sci & Technol, Dept Mat Sci & Engn, Shenzhen 518055, Peoples R China
  • [ 11 ] [Wang, Lina]Southern Univ Sci & Technol, Guangdong Prov Key Lab Computat Sci & Mat Design, Shenzhen 518055, Peoples R China
  • [ 12 ] [Luo, Guangfu]Southern Univ Sci & Technol, Guangdong Prov Key Lab Computat Sci & Mat Design, Shenzhen 518055, Peoples R China
  • [ 13 ] [Yu, Zhiyang]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China
  • [ 14 ] [Rummeli, Mark H.]Soochow Univ, Key Lab Adv Carbon Mat & Wearable Energy Technol, Soochow Inst Energy & Mat Innovat SIEMIS, Coll Energy, Suzhou 215006, Peoples R China
  • [ 15 ] [Rummeli, Mark H.]Polish Acad Sci, Ctr Polymer & Carbon Mat, M Curie Sklodowskiej 34, PL-41819 Zabrze, Poland
  • [ 16 ] [Rummeli, Mark H.]VSB Tech Univ Ostrava, Inst Environm Technol, 17 Listopadu 15, Ostrava 70833, Czech Republic
  • [ 17 ] [Rummeli, Mark H.]Helmholtzstr 20, D-01069 Dresden, Germany

Reprint 's Address:

  • [Wang, Ming-Sheng]Xiamen Univ, Coll Chem & Chem Engn, Coll Mat, State Key Lab Phys Chem Solid Surfaces Coll Mat, Xiamen 361005, Peoples R China

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Source :

ADVANCED MATERIALS

ISSN: 0935-9648

Year: 2021

Issue: 51

Volume: 33

3 2 . 0 8 6

JCR@2021

2 7 . 4 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:142

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 21

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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