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author:

Lin, Jiaojuan (Lin, Jiaojuan.) [1] | Xie, Yonghui (Xie, Yonghui.) [2] | Yang, Tengjun (Yang, Tengjun.) [3] | Zheng, Wenrui (Zheng, Wenrui.) [4] | Huang, Zewei (Huang, Zewei.) [5] | Zhang, Hong (Zhang, Hong.) [6] | Wang, Xinghui (Wang, Xinghui.) [7]

Indexed by:

SCIE

Abstract:

Lithium metal is a promising anode material for high-energy-density batteries due to its exceptionally high theoretical capacity. However, challenges such as non-uniform deposition of lithium during charge/discharge cycling, which leads to the growth of lithium dendrites, impede the commercialization of lithium-metal anodes. Herein, we developed a lithophilic NiCo2O4 (NCO) nanoneedle-modified carbonized cotton napkin (CCN) to serve as a low-cost and lightweight interlayer for lithium metal anodes. The three-dimensional carbon network provides superior electronic and ionic conductivity, while the high lithiophilicity of NCO effectively reduces the nucleation overpotential of lithium and suppresses dendrite formation. Consequently, the NCO@CCN-Li symmetric cell demonstrates a stable cycling performance of 700 h at 20 mA cm- 2/10 mAh cm- 2 and maintains a stable cycle for 350 h even when the current density is increased to 40 mA cm- 2. Furthermore, the full cell paired with the LiFePO4 cathode (10.5 mg cm- 2) retains a discharge specific capacity of 134.5 mAh g- 1 after 200 cycles, with a capacity retention rate of 99.6 % and a coulombic efficiency of 99.7 %. This work provides valuable insights for the development of high-energy-density lithium-metal batteries.

Keyword:

Bimetallic oxide Carbon material Lithiophilic interlayer Lithium dendrites Lithium-metal batteries

Community:

  • [ 1 ] [Lin, Jiaojuan]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Xie, Yonghui]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 3 ] [Yang, Tengjun]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 4 ] [Zheng, Wenrui]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 5 ] [Huang, Zewei]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 6 ] [Zhang, Hong]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 7 ] [Wang, Xinghui]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 8 ] [Wang, Xinghui]Jiangsu Collaborat Innovat Ctr Photovolta Sci & En, Changzhou 213000, Peoples R China

Reprint 's Address:

  • [Wang, Xinghui]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China

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Source :

JOURNAL OF POWER SOURCES

ISSN: 0378-7753

Year: 2025

Volume: 645

8 . 1 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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