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Abstract:
High density Ba4Sm2Fe2Nb8O30 (BSFN) multiferroics ceramics with tetragonal tungsten bronze structure had been prepared by microwave sintering (MS) for 30min and conventional sintering (CS) methods for 4 h at 1275 degrees C. Single tungsten bronze phase and equiaxial grains are obtained for the MS BSFN ceramics, while a small amount secondary phase of SmNbO4 is observed in the CS BSFN ceramics with columnar grains. Compared to Ba4Sm2Fe2Nb8O30 ceramics prepared by CS method, enhanced dielectric, ferroelectric and magnetic properties are achieved for the MS BSFN ceramics. The values of electric polarization Pr and coercive electric field Ec are 2.11 mu C/cm2 and 7.14 kV/cm for the MS BSFN ceramics, respectively. Meantime, the magnetic polarization Mr of 0.410emu/g and coercive magnetic field Hc of 2930Oe are also obtained for the MS BSFN ceramics. Based on the density, crystal structure, point defect and grain, the reasons of enhanced dielectric, ferroelectric and magnetic properties are discussed for the MS BSFN ceramics It is indicated that Ba4Sm2Fe2Nb8O30 is an intrinsic room temperature multiferroic materials.
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CERAMICS INTERNATIONAL
ISSN: 0272-8842
Year: 2021
Issue: 15
Volume: 47
Page: 21024-21028
5 . 5 3 2
JCR@2021
5 . 1 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:142
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 4
SCOPUS Cited Count: 6
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2