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author:

Yuan, Chongyang (Yuan, Chongyang.) [1] | Chen, Wei (Chen, Wei.) [2] | Yang, Zunxian (Yang, Zunxian.) [3] (Scholars:杨尊先) | Huang, Zhenguo (Huang, Zhenguo.) [4] | Yu, Xuebin (Yu, Xuebin.) [5]

Indexed by:

EI Scopus SCIE CSCD

Abstract:

MgH2 is regarded as a potential hydrolysis material for the hydrogen generation due to its high theoretical hydrogen yield, abundant source on earth and environmentally friendly hydrolysates. However, the quickly formed passive magnesium hydroxide layer on the surface of MgH2 will hinder its further hydrolysis reaction, leading to sluggish reaction kinetics and low H-2 yield. In this paper, we explore the improvement of different anions and cations in solutions for the hydrolysis of MgH2. It is found that the cations in the solution promote the reaction rate of MgH2 hydrolysis through the hydrolysate-induced growth effect, among which the fastest hydrogen yield can get 1664 mL/g within a few minutes in the Fe-2(SO4)(3) solution. As for the anions, it enables different microstructures of the Mg(OH)(2) hydrolysate which give rise to enhanced water utilization. Specially, for the mixed 0.5 M MgCl2 + 0.05 M MgSO4 solution, the water utilization rate attains the optimum value of 51.3 %, much higher than that of the single MgCl2 or MgSO4 solutions. These findings are of great significance for the application of MgH2 hydrolysis as hydrogen generation. (C) 2021 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.

Keyword:

Anions Cations Hydrogen generation Hydrolysis reaction MgH2

Community:

  • [ 1 ] [Yuan, Chongyang]Fudan Univ, Dept Mat Sci, Shanghai 200433, Peoples R China
  • [ 2 ] [Chen, Wei]Fudan Univ, Dept Mat Sci, Shanghai 200433, Peoples R China
  • [ 3 ] [Yu, Xuebin]Fudan Univ, Dept Mat Sci, Shanghai 200433, Peoples R China
  • [ 4 ] [Yang, Zunxian]Fuzhou Univ, Natl & Local United Engn Lab Flat Panel Display T, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Huang, Zhenguo]Univ Technol Sydney, Sch Civil & Environm Engn, Ultimo, NSW 2007, Australia

Reprint 's Address:

  • 杨尊先

    [Yu, Xuebin]Fudan Univ, Dept Mat Sci, Shanghai 200433, Peoples R China;;[Yang, Zunxian]Fuzhou Univ, Natl & Local United Engn Lab Flat Panel Display T, Fuzhou 350002, Fujian, Peoples R China

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Source :

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY

ISSN: 1005-0302

CN: 21-1315/TG

Year: 2021

Volume: 73

Page: 186-192

1 0 . 3 1 9

JCR@2021

1 1 . 2 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:142

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 38

SCOPUS Cited Count: 43

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 7

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