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author:

Fan, Jianming (Fan, Jianming.) [1] | Xiong, Jinhua (Xiong, Jinhua.) [2] | Liu, Dayue (Liu, Dayue.) [3] | Tang, Yuanping (Tang, Yuanping.) [4] | He, Song (He, Song.) [5] | Hu, Zhibiao (Hu, Zhibiao.) [6]

Indexed by:

EI SCIE

Abstract:

A novel strategy was developed to fabricate a CdS/Pt photocatalyst (defined as CdS/w%Pt-PAR) via the cathodic photocorrosion effect of CdS. A tentative mechanism for Pt deposition on CdS via the cathodic photocorrosion effect was proposed, based on a series of electrochemical characterization methods, such as cyclic voltammetry and Mott-Schottky tests. Transmission electron microscopy verified that Pt was grafted on the CdS surface via a heterojunction. Moreover, a strong interaction between Pt and CdS was further confirmed by X-ray photoelectron spectroscopy. The optimal photocatalytic H-2 evolution rate of CdS/2%Pt-PAR was 1086.1 mu mol h(-1), 6.4 and 2.6 fold higher than that of the reference samples synthesized by traditional photodeposition (CdS/2%Pt-PD) and chemical reduction (CdS/2%Pt-CR) methods, respectively. Linear sweep voltammetry and fluorescence experiments verified that CdS/2%Pt-PAR has a lower H-2 evolution overpotential and faster separation of photogenerated carriers, respectively, compared with CdS/2%Pt-PD and CdS/2%Pt-CR. This work paves a new route for fabricating CdS/metal photocatalysts with highly efficient and stable photocatalytic H-2 evolution activity.

Keyword:

Community:

  • [ 1 ] [Fan, Jianming]Longyan Univ, Fujian Prov Key Lab Clean Energy Mat, Longyan 364000, Peoples R China
  • [ 2 ] [Xiong, Jinhua]Longyan Univ, Fujian Prov Key Lab Clean Energy Mat, Longyan 364000, Peoples R China
  • [ 3 ] [Liu, Dayue]Longyan Univ, Fujian Prov Key Lab Clean Energy Mat, Longyan 364000, Peoples R China
  • [ 4 ] [Tang, Yuanping]Longyan Univ, Fujian Prov Key Lab Clean Energy Mat, Longyan 364000, Peoples R China
  • [ 5 ] [He, Song]Longyan Univ, Fujian Prov Key Lab Clean Energy Mat, Longyan 364000, Peoples R China
  • [ 6 ] [Hu, Zhibiao]Longyan Univ, Fujian Prov Key Lab Clean Energy Mat, Longyan 364000, Peoples R China
  • [ 7 ] [Xiong, Jinhua]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 熊锦华

    [Xiong, Jinhua]Longyan Univ, Fujian Prov Key Lab Clean Energy Mat, Longyan 364000, Peoples R China;;[Hu, Zhibiao]Longyan Univ, Fujian Prov Key Lab Clean Energy Mat, Longyan 364000, Peoples R China;;[Xiong, Jinhua]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China

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Source :

NEW JOURNAL OF CHEMISTRY

ISSN: 1144-0546

Year: 2021

Issue: 23

Volume: 45

Page: 10315-10324

3 . 9 2 5

JCR@2021

2 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:117

JCR Journal Grade:2

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 11

SCOPUS Cited Count: 12

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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