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Abstract:
A tetratellurium-substituted heteropolyoxoniobate with the formula K2H[Cu(phen)(H2O)](4)[Cu(phen)](2)[(LiNb8Te4O40)]center dot 34H(2)O (1; phen = 1,10-phenanthroline) was hydrothermally prepared and structurally characterized. The compound represents the first hexavalent tellurium-substituted Keggin-type polyoxometalate (POM) so far. What is more, the POM cluster in 1 can elaborately self-assemble into a stable supramolecular framework with an ion conduction property through unique intermolecular pi-pi stacking.
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INORGANIC CHEMISTRY
ISSN: 0020-1669
Year: 2021
Issue: 9
Volume: 60
Page: 6162-6166
5 . 4 3 6
JCR@2021
4 . 3 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:117
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 11
SCOPUS Cited Count: 6
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2