A Tellurium-Substituted Heteropolyniobate with Unique π-πStacking and Ionic Conduction Property - Details

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A　tetratellurium-substituted　heteropolyoxoniobate　with　the　formula　K2H[Cu(phen)(H2O)]4[Cu(phen)]2[(LiNb8Te4O40)]·34H2O　(1;　phen　=　1,10-phenanthroline)　was　hydrothermally　prepared　and　structurally　characterized.　The　compound　represents　the　first　hexavalent　tellurium-substituted　Keggin-type　polyoxometalate　(POM)　so　far.　What　is　more,　the　POM　cluster　in　1　can　elaborately　self-assemble　into　a　stable　supramolecular　framework　with　an　ion　conduction　property　through　unique　intermolecular　π-πstacking.　©　2021　American　Chemical　Society.　All　rights　reserved.

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Polyoxometalates Tellurium Tellurium compounds

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[ 1 ] [Wu, Ping-Xin]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian; 350108, China
[ 2 ] [Lai, Rong-Da]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian; 350108, China
[ 3 ] [Ge, Rui]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian; 350108, China
[ 4 ] [Sun, Cai]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian; 350108, China
[ 5 ] [Wang, Guo-Qiang]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian; 350108, China
[ 6 ] [Li, Xin-Xiong]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian; 350108, China
[ 7 ] [Li, Xin-Xiong]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian; 350002, China
[ 8 ] [Zheng, Shou-Tian]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian; 350108, China

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Source ：

Inorganic Chemistry

ISSN： 0020-1669

Year： 2021

Issue： 9

Volume： 60

Page： 6162-6166

5 . 4 3 6

JCR@2021

4 . 3 0 0

JCR@2023

ESI HC Threshold：117

JCR Journal Grade：1

CAS Journal Grade：1

Cited Count：

WoS CC Cited Count： 0

SCOPUS Cited Count： 5

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 2

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