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author:

Li, Jian (Li, Jian.) [1] | Li, Lei (Li, Lei.) [2] | Xu, Yilin (Xu, Yilin.) [3] | Zhu, Junyong (Zhu, Junyong.) [4] | Liu, Fei (Liu, Fei.) [5] | Shen, Jiangnan (Shen, Jiangnan.) [6] | Wang, Zhenyu (Wang, Zhenyu.) [7] | Lin, Jiuyang (Lin, Jiuyang.) [8]

Indexed by:

EI SCIE

Abstract:

Thin film nanocomposite (TFN) membrane, which consists of nanofiller embedded polyamide layer and a porous substrate, have been deemed as a promising candidate to achieve multifunctionality, property enhancement and controllable separation process. Being different from traditional interfacial polymerization synthesis process, this work attempts to use MXene nanosheets as nanofillers on membranes surface while polyamide constructed by interfacial polymerization is served as intercalate reagent and stabilizer. The positively charged polyethyleneimine (PEI) and negatively charged MXene nanosheets guaranteed a favorable compatibility, which finally endowed the obtained membranes with high rejection toward different dyes. The optimal membrane decorated by 0.1 mg PEI and 0.15 mg MXene possesses a pure water permeability of 20.9 LMH bar(-1) and dyes rejection of 99.42%, 99.02% and 98.84% for Congo red, Reactive blue 19 and Methyl blue, respectively. Meantime, the membrane exhibited impressive rejections towards Na2SO4 and NaCl (65.7% and 23.9%). The enhanced performance of the MXene-based membrane is mainly due to the amplified interlayer distance and the appropriate crosslinking degree, which increases the water transport and retain the rejection simultaneously. Overall, this work suggests that the employment of MXene nanosheets for the construction of high-performance nanofiltration membranes can be a successful choice to treat dye wastewater.

Keyword:

Dye removal Dye/salt separation Enhanced permselectivity MXene Thin film nanocomposite

Community:

  • [ 1 ] [Li, Jian]Jiangnan Univ, Sch Environm & Civil Engn, Lab Environm Biotechnol, Wuxi 214122, Peoples R China
  • [ 2 ] [Li, Lei]Jiangnan Univ, Sch Environm & Civil Engn, Lab Environm Biotechnol, Wuxi 214122, Peoples R China
  • [ 3 ] [Wang, Zhenyu]Jiangnan Univ, Sch Environm & Civil Engn, Lab Environm Biotechnol, Wuxi 214122, Peoples R China
  • [ 4 ] [Xu, Yilin]Nanyang Technol Univ, Nanyang Environm & Water Res Inst, Singapore Membrane Technol Ctr, 1 Cleantech Loop, Singapore 637141, Singapore
  • [ 5 ] [Zhu, Junyong]Zhengzhou Univ, Sch Chem Engn & Energy, Zhengzhou 450001, Peoples R China
  • [ 6 ] [Liu, Fei]Jiangnan Univ, State Key Lab Food Sci & Technol, Wuxi 214122, Peoples R China
  • [ 7 ] [Liu, Fei]Jiangnan Univ, Sch Food Sci & Technol, Wuxi 214122, Peoples R China
  • [ 8 ] [Shen, Jiangnan]Zhejiang Univ Technol, Chem Engn Coll, Hangzhou 310014, Peoples R China
  • [ 9 ] [Lin, Jiuyang]Fuzhou Univ, Fujian Prov Engn Res Ctr Rural Waste Recycling Te, Sch Environm & Resources, Fuzhou 350116, Peoples R China

Reprint 's Address:

  • [Wang, Zhenyu]Jiangnan Univ, Sch Environm & Civil Engn, Lab Environm Biotechnol, Wuxi 214122, Peoples R China;;[Shen, Jiangnan]Zhejiang Univ Technol, Chem Engn Coll, Hangzhou 310014, Peoples R China

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Source :

CHEMICAL ENGINEERING JOURNAL

ISSN: 1385-8947

Year: 2022

Volume: 427

1 5 . 1

JCR@2022

1 3 . 4 0 0

JCR@2023

ESI Discipline: ENGINEERING;

ESI HC Threshold:66

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 45

SCOPUS Cited Count: 48

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

Online/Total:246/10044500
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