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author:

Ma, Zheng-Wei (Ma, Zheng-Wei.) [1] | Zhang, Kai-Ning (Zhang, Kai-Ning.) [2] | Zou, Zhi-Jin (Zou, Zhi-Jin.) [3] | Lü, Qiu-Feng (Lü, Qiu-Feng.) [4]

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EI

Abstract:

A novel activated carbon (CCH-TS) derived from chitosan hydrogel (CH) coated tea saponin (TS) was prepared to investigate its removal performance for methylene blue (MB). CCH-TS was characterized by thermogravimetric analysis, field-emission scanning electron microscope, fourier transform infrared spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, Brunauer-Emmett-Teller, and zeta potential analysis. The results showed that CCH-TS had a high specific area of 3504 m2/g with a large pore volume of 6.03 m3/g. In the batch mode adsorption experiments, the effects of initial pH values, adsorbent concentration, initial MB concentration and contact time, and adsorption temperature on the adsorption performance of CCH-TS for MB were studied. The experimental results were fitted by pseudo-first-order kinetic, pseudo-second-order kinetic and intra-particle diffusion models. Furthermore, Langmuir, Freundlich and Temkin isotherms were employed to analyze the equilibrium adsorption data. It was found that these data were fitted to Langmuir isotherm best with a maximum adsorption capacity of 604.10 mg/g, while pseudo-second-order kinetic model could describe the adsorption process more accurately. Thermodynamic analysis implied that the adsorption process was spontaneous and exothermic. Therefore, a facile one-step route to preparation of activated carbon with a high specific area and efficient dye removal ability was achieved. © 2021 Elsevier Ltd.

Keyword:

Activated carbon Adsorption Chitosan Fourier transform infrared spectroscopy Hydrogels Isotherms Kinetics Scanning electron microscopy Tea Thermoanalysis Thermogravimetric analysis X ray photoelectron spectroscopy

Community:

  • [ 1 ] [Ma, Zheng-Wei]Key Laboratory of Advanced Materials Technology, Fuzhou University, Fujian Province University, College of Materials Science and Engineering, 2 Xueyuan Road, Fuzhou; 350116, China
  • [ 2 ] [Zhang, Kai-Ning]Key Laboratory of Advanced Materials Technology, Fuzhou University, Fujian Province University, College of Materials Science and Engineering, 2 Xueyuan Road, Fuzhou; 350116, China
  • [ 3 ] [Zou, Zhi-Jin]Key Laboratory of Advanced Materials Technology, Fuzhou University, Fujian Province University, College of Materials Science and Engineering, 2 Xueyuan Road, Fuzhou; 350116, China
  • [ 4 ] [Lü, Qiu-Feng]Key Laboratory of Advanced Materials Technology, Fuzhou University, Fujian Province University, College of Materials Science and Engineering, 2 Xueyuan Road, Fuzhou; 350116, China

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Source :

Journal of Environmental Chemical Engineering

Year: 2021

Issue: 3

Volume: 9

7 . 9 6 8

JCR@2021

7 . 4 0 0

JCR@2023

ESI HC Threshold:105

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 36

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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