The　tailor-prepare　solid　phase　microextraction　(SPME)　coatings　with　stable　and　excellent　properties　to　effectively　extract　analytes　from　sample　matrix　still　remains　a　challenge.　Herein,　a　nitrogen　doped　graphitic　carbon　networks　(NG-CNTW)　coated　fiber　was　fabricated　by　direct　carbonization　of　nanosized　ZIF-67　crystals　(nano-ZIF-67)　that　grown　on　stainless　steel　wire.　The　NG-CNTW　coated　fiber　coupled　with　gas　chromatography-tandem　mass　spectrometry　(GC-MS/MS)　was　applied　for　enrichment　and　determination　of　pyrethroids.　The　NG-CNTW　coating　exhibited　high　surface　area　and　hierarchical　porous　structures　that　facilitate　diffusion　and　accessibility　of　target　molecules.　Simultaneously,　the　nitrogen　doped　and　highly　graphitic　structures　endow　the　coating　with　high　adsorption　affinity　for　aromatic　compounds.　Under　optimum　conditions,　the　SPME-GC-MS/MS　method　presented　wide　range　of　linearity　performance　(0.08–200.0　ng　g−1),　low　limits　of　detection　(0.02–0.5　ng　g−1)　and　good　repeatability　(RSD　−1and　2.08–9.29　ng　g−1,　respectively.　This　work　not　only　provides　a　new　method　by　fabricating　carbon　nanomaterial　coatings　in　situ　derived　from　MOFs,　but　also　shows　great　potential　of　MOFs　derivative　materials　in　environmental　analysis　field.　©　2021　Elsevier　B.V.