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author:

Han, Songjie (Han, Songjie.) [1] | Li, Ziping (Li, Ziping.) [2] | Ma, Si (Ma, Si.) [3] | Zhi, Yongfeng (Zhi, Yongfeng.) [4] | Xia, Hong (Xia, Hong.) [5] | Chen, Xiong (Chen, Xiong.) [6] | Liu, Xiaoming (Liu, Xiaoming.) [7]

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Abstract:

Metal-free conjugated microporous polymers (CMPs) as visible-light active and recyclable photocatalysts offer a green and sustainable alternative to classical metal-based photosensitizers. However, the strategy for screening CMP-based heterogeneous photocatalysts has not been interpreted up to now. Herein, we present a general strategy for obtaining excellent solid photocatalysts, which is to implement bandgap engineering in the same series of materials. As a proof of concept, three conjugated porous materials containing benzo[1,2-b:3,4-b′:5,6-b′′]trithiophene building blocks (BTT-CMP1, BTT-CMP2 and BTT-CMP3) were successfully constructed. They possess permanent porosity with a large specific surface area and excellent stability. By changing the linker between benzotrithiophene units, the bandgaps, energy levels and photoelectric performances including the absorption, transient photocurrent responses and photocatalytic performances of BTT-CMPs could be handily modulated. Indeed, BTT-CMP2 displayed the best catalytic activity for visible-light-induced synthesis of benzimidazoles among the three CMP materials, even higher than that of small molecule photocatalysts. As a metal-free photocatalyst, interestingly, the screened BTT-CMP2 also showed extensive substrate applicability and outstanding recyclability. Additionally, we have the opinion that this strategy will prove to be a guiding principle for screening superior CMP-based photocatalysts and broaden their application fields. © The Royal Society of Chemistry 2020.

Keyword:

Catalyst activity Conjugated polymers Energy gap Light Metals Microporosity Photocurrents Photosensitizers Porous materials Synthesis (chemical)

Community:

  • [ 1 ] [Han, Songjie]College of Chemistry, Jilin University, Changchun; 130012, China
  • [ 2 ] [Li, Ziping]College of Chemistry, Jilin University, Changchun; 130012, China
  • [ 3 ] [Ma, Si]College of Chemistry, Jilin University, Changchun; 130012, China
  • [ 4 ] [Zhi, Yongfeng]College of Chemistry, Jilin University, Changchun; 130012, China
  • [ 5 ] [Xia, Hong]State Key Laboratory on Integrated Optoelectronics, College of Electronic Science and Technology, Jilin University, Changchun; 130012, China
  • [ 6 ] [Chen, Xiong]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou; 350002, China
  • [ 7 ] [Liu, Xiaoming]College of Chemistry, Jilin University, Changchun; 130012, China

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Source :

Journal of Materials Chemistry A

ISSN: 2050-7488

Year: 2021

Issue: 6

Volume: 9

Page: 3333-3340

1 4 . 5 1 1

JCR@2021

1 0 . 8 0 0

JCR@2023

ESI HC Threshold:142

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 69

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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